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Investigations of Charge Migration and Charge Trapping in Fatigued Organic Photoconductors

机译:疲劳有机光电导体中电荷迁移和电荷陷阱的研究

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This article presents the experimental photodischarge kinetics of electrostatically fatigued dual-layer organic photoconductors characterized by an electrophotographic incremental charging technique that reveals the differences in the photoconductor charging profiles. During normal operation, 15% of the holes that migrate to the surface after photodischarge are not neutralized by the negative surface ions. The accumulation of these lingering surface charges (charge transport material radical cations) manifests itself as defects in half-tone images, as either missing or reduced size dots or lines. In the presence of corona gases, these surface holes oxidize and reduce the energy barrier for hole injection from a positively charged surface, e.g., contact with a transfer roller. These injected holes accumulate near the charge generation layer and require twice the amount of negative charge to attain the same surface potential as that of a new organic photoconductor (OPC) drum. The damaged depth of this injection region extends to about 50 nm into the OPC surface and is easily removed by the printer's abrasion mechanisms (e.g., cleaning blade, toner, paper). ?2012 Society for Imaging Science and Technology.
机译:本文介绍了以电子照相增量充电技术为特征的静电疲劳双层有机光电导体的实验光放电动力学,揭示了光电导体充电曲线的差异。在正常操作期间,光放电后迁移到表面的15%的孔不会被负表面离子中和。这些挥之不去的表面电荷(电荷传输材料自由基阳离子)的积累本身表现为半色调图像中的缺陷,表现为点或线的丢失或缩小。在存在电晕气体的情况下,这些表面孔会氧化并减少从带正电的表面(例如与转印辊接触)进行空穴注入的能垒。这些注入的空穴聚集在电荷产生层附近,并且需要两倍的负电荷量才能获得与新有机光电导体(OPC)感光鼓相同的表面电势。该注入区域的损坏深度延伸到OPC表面约50 nm,并且很容易通过打印机的磨损机制(例如清洁刮板,墨粉,纸张)清除。 2012年影像科学与技术学会。

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