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Enhancement of silver nuclei formation by sulfur sensitization centers on silver bromide grains

机译:硫敏化中心在溴化银晶粒上增强银核的形成

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摘要

Heavy hydrogen hypersensitization formed P centers, which were silver nuclei acting as electron traps on octahedral silver bromide grains in coated emulsion layers. The number of P centers was evaluated by measuring the diffuse reflectance spectrum of a stack of 10 coated emulsion layers. Sulfur sensitization centers increased the rate of formation of P centers, and decreased its activation energy. The observed activation energies were 0.87 eV in a primitive emulsion and 0.52 eV in an excessively sulfur sensitized one. This result supports an idea that sulfur sensitization centers formed on silver bromide emulsion grains catalyze silver nuclei formation, and that this is one of the essential functions of sulfur sensitization centers.
机译:重氢超敏反应形成了P中心,P中心是银核,在涂层乳剂层的八面体溴化银晶粒上充当电子陷阱。通过测量10个涂覆的乳剂层的堆叠的漫反射光谱来评估P中心的数量。硫敏化中心增加了P中心的形成速率,并降低了其活化能。观察到的活化能在原始乳剂中为0.87 eV,在过度硫敏感的乳剂中为0.52 eV。该结果支持这样的想法,即在溴化银乳剂颗粒上形成的硫敏化中心催化银核的形成,并且这是硫敏化中心的基本功能之一。

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