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Facile preparation of three-dimensional honeycomb nitrogen-doped carbon materials for supercapacitor applications

机译:用于超级电容器应用的三维蜂窝氮掺杂碳材料的舒适性

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摘要

The preparation of three-dimensional honeycomb nitrogen-doped carbon materials (3D-HNCMs) which can be used as electrode materials for supercapacitors is reported. The composites with the 3D honeycomb structure exhibited better electrochemical performance, and the structure and properties were proved by various means, such as SEM, TEM, IR, N-2 sorption, XRD and XPS. Used as electrode materials for supercapacitors in the KOH electrolyte, 3D-HNCMs displayed a significantly high specific capacitance (409 F/g at a current of 0.5 A/g). Moreover, the 3D-HNCM electrode exhibited superior electrochemical performance, such as excellent cycling stability (98% capacitance retention after 10,000 cycles), a maximum energy density of 15.37 W h/kg, a maximum power density of 40.3 kW/kg, and low equivalent series resistance (2.1 X). Particularly, the electrochemical characteristic of 3D-HNCMs could be attributed to the synergistic effect of a high surface area, unique microporous and mesoporous structure, and nitrogen atom doping. These carbon materials with unique structure are promising electrode materials for future supercapacitor application.
机译:据报道,制备三维蜂窝氮掺杂碳材料(3D-HNCM),其可用作超级电容器的电极材料。具有3D蜂窝结构的复合材料表现出更好的电化学性能,并且通过各种方法证明了结构和性质,例如SEM,TEM,IR,N-2吸附,XRD和XPS。用作KOH电解质中超级电容器的电极材料,3D-HNCMS显示出明显高的比电容(在0.5A / g的电流下409 f / g)。此外,3D-HNCM电极表现出优异的电化学性能,例如优异的循环稳定性(在10,000个循环后98%电容保留),最大能量密度为15.37WH / kg,最大功率密度为40.3kW / kg,低等效串联电阻(2.1 x)。特别地,3D-HNCMS的电化学特性可能归因于高表面积,独特的微孔和中孔结构和氮原子掺杂的协同效应。这些具有独特结构的碳材料是未来超级电容器应用的电极材料。

著录项

  • 来源
    《Journal of Materials Research》 |2019年第7期|1200-1209|共10页
  • 作者单位

    Northwest Normal Univ Coll Chem & Chem Engn Res Ctr Gansu Mil & Civilian Integrat Adv Struct Lanzhou 730070 Gansu Peoples R China;

    Northwest Normal Univ Coll Chem & Chem Engn Res Ctr Gansu Mil & Civilian Integrat Adv Struct Lanzhou 730070 Gansu Peoples R China;

    Northwest Normal Univ Coll Chem & Chem Engn Res Ctr Gansu Mil & Civilian Integrat Adv Struct Lanzhou 730070 Gansu Peoples R China;

    Northwest Normal Univ Coll Chem & Chem Engn Res Ctr Gansu Mil & Civilian Integrat Adv Struct Lanzhou 730070 Gansu Peoples R China;

    Northwest Normal Univ Coll Chem & Chem Engn Res Ctr Gansu Mil & Civilian Integrat Adv Struct Lanzhou 730070 Gansu Peoples R China;

    Northwest Normal Univ Coll Chem & Chem Engn Res Ctr Gansu Mil & Civilian Integrat Adv Struct Lanzhou 730070 Gansu Peoples R China;

    Northwest Normal Univ Coll Chem & Chem Engn Res Ctr Gansu Mil & Civilian Integrat Adv Struct Lanzhou 730070 Gansu Peoples R China;

    Northwest Normal Univ Coll Chem & Chem Engn Res Ctr Gansu Mil & Civilian Integrat Adv Struct Lanzhou 730070 Gansu Peoples R China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    composite; nanostructure; chemical composition;

    机译:复合;纳米结构;化学成分;

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