首页> 外文期刊>Journal of Materials Research >Microstructural evolution and wear performance of the high-entropy FeMnCoCr alloy/TiC/CaF_2 self-lubricating composite coatings on copper prepared by laser cladding for continuous casting mold
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Microstructural evolution and wear performance of the high-entropy FeMnCoCr alloy/TiC/CaF_2 self-lubricating composite coatings on copper prepared by laser cladding for continuous casting mold

机译:通过铸模激光覆层制备的高熵叶胚凝块/ TiC / CAF_2自润滑复合涂层的微观结构演化与磨损性能

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摘要

The FeMnCoCr high-entropy alloy/TiC/CaF2 self-lubricating coatings were successfully prepared on a Cu-Zr-Cr alloy for continuous casting mold by laser cladding for wear-resistance. The intriguing finding was that the laser-cladded FeMnCoCr is mainly composed of face-centered cubic and hexagonal close-packed solid solution phases. During the cladding process, the FeMnCoCr/TiC or the FeMnCoCr/TiC/CaF2 mixed sufficiently with Cu matrix, while FeMnCoCr exhibited a spherical shape owing to being insoluble in Cu. The average hardness of the FeMnCoCr/TiC/CaF2 self-lubricating high-entropy alloy (HEA) coatings was twice that of the pure FeMnCoCr HEA coating. By addition of TiC, the friction coefficient and wear rate were decreased from 0.35 and 3.68 x 10(-15) mm(3)/m to 0.27 and 3.06 x 10(-15) mm(3)/m, respectively. When CaF2 was added, the friction coefficients and wear rate were decreased to 0.16 and 2.16 x 10(-15) mm(3)/m, respectively, which was 54% lower than the pure FeMnCoCr HEA coating. The main wear mechanism of the FeMnCoCr coating is abrasive wear while that of the FeMnCoCr/TiC coating is abrasive and adhesion wear. But adhesion wear is dominant for the FeMnCoCr/TiC/CaF2 coating.
机译:通过激光包层成功地在Cu-Zr-Cr合金上成功制备了毫流高熵合金/ TiC / CAF2自润滑涂层,通过激光熔接进行耐磨性。有趣的发现是激光包覆的幻线组主要由面为中心的立方和六边形近填充固溶液相组成。在包层过程中,毫流/ TIC或毫流/ TIC / CAF2与Cu矩阵充分混合,而毫花癌由于不溶于Cu而表现出球形。 Femncocroc / TiC / CAF2自润滑高熵合金(Hea)涂层的平均硬度是纯Femncog Zh涂层的两倍。通过添加TiC,摩擦系数和磨损率分别从0.35和3.68×10(-15)mm(3)/ m至0.27和3.06×10(-15)mm(3)/ m。当加入CAF2时,分别将摩擦系数和磨损率降低至0.16和2.16×10(-15)mm(3)/ m,比纯FemncogRe Hea涂层低54%。毫流涂层的主磨损机构是磨料磨损,而毫流/涂层的涂层是磨料和粘附磨损。但纤维化/ TIC / CAF2涂层的粘连磨损是占主导地位。

著录项

  • 来源
    《Journal of Materials Research》 |2019年第10期|1714-1725|共12页
  • 作者单位

    Cent S Univ High Strength Struct Mat Lab State Key Lab Powder Met Sci & Technol Changsha 410083 Hunan Peoples R China;

    Cent S Univ High Strength Struct Mat Lab State Key Lab Powder Met Sci & Technol Changsha 410083 Hunan Peoples R China;

    Cent S Univ High Strength Struct Mat Lab State Key Lab Powder Met Sci & Technol Changsha 410083 Hunan Peoples R China;

    Cent S Univ High Strength Struct Mat Lab State Key Lab Powder Met Sci & Technol Changsha 410083 Hunan Peoples R China;

    Cent S Univ High Strength Struct Mat Lab State Key Lab Powder Met Sci & Technol Changsha 410083 Hunan Peoples R China;

    Cent S Univ High Strength Struct Mat Lab State Key Lab Powder Met Sci & Technol Changsha 410083 Hunan Peoples R China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    laser cladding; high-entropy alloy coatings; solid lubrication;

    机译:激光包层;高熵合金涂层;固体润滑;

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