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Copper- and nickel-based flexible polyester electrodes for energy storage devices

机译:用于储能装置的铜和镍的柔性聚酯电极

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摘要

Lightweight, inexpensive and flexible electrodes are required for flexible technological applications. As polymers are generally low cost, flexible and have low density, they are potential candidates for use as flexible electrodes. However, polymers are not conductive and thus cannot be used as electrodes or current collectors. Polymers have been coated by metals/alloys to make them conductive for use in various applications including electromagnetic shielding and sensors. In this work, a flexible electrode was successfully fabricated by electrodeposition of Cu and Ni on polyester fabric for an energy storage application. The growth of metals was carried out in non-aqueous ionic liquid electrolyte, with the deposition condition of Cu and Ni studied by means of cyclic voltammetry. Non-electrochemical (FTIR, XRD, SEM and EDAX) characterizations of the metal-coated polyester are also presented. Modified flexible electrodes were transferred to an alkaline electrolyte for electrochemical characterization. The specific capacitance of Cu- and Ni-coated polyester reached 33.4 F/g and 50.2 F/g at the same scan rate of 5 mV/s. These results suggest an inexpensive and straightforward method for the fabrication of a flexible electrode for energy storage applications.
机译:灵活的技术应用需要轻量级,便宜且柔性的电极。随着聚合物的成本通常是低成本,柔性且具有低密度,它们是潜在的候选者,用作柔性电极。然而,聚合物不导电,因此不能用作电极或电流收集器。金属/合金涂覆聚合物,使它们用于各种应用,包括电磁屏蔽和传感器。在这项工作中,通过Cu和Ni的涤纶织物的电沉积成功地制造了一种柔性电极,用于储能施加。金属的生长在非水离子液体电解质中进行,Cu和Ni的沉积条件通过环状伏安法研究。还介绍了金属涂层聚酯的非电化学(FTIR,XRD,SEM和EDAX)表征。将改性的柔性电极转移到用于电化学表征的碱性电解质中。 Cu-和Ni涂层聚酯的比电容以5mV / s的相同扫描速率达到33.4f / g和50.2 f / g。这些结果表明,用于制造柔性电极的廉价和直接的方法,用于储能应用。

著录项

  • 来源
    《Journal of Materials Research》 |2020年第16期|2115-2125|共11页
  • 作者

    Abdulcabbar Yavuz;

  • 作者单位

    Engineering Faculty Metallurgical and Materials Engineering Department Gaziantep University Sehitkamil 27310 Gaziantep Turkey;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
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