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Hydrothermal synthesis of star-shaped Bi_5O_7Br catalysts with strong visible light catalytic performance

机译:具有强可见光催化性能的星状Bi_5O_7BR催化剂的水热合成

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摘要

Micron star-shaped Bi_5O_7Br catalysts were synthesized, with Bi(NO_3)_3·5H_2O and cetyltrimethylammonium bromide (CTAB) as raw materials, by using a simple hydrothermal method. X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), and UV-visible diffuse reflectance spectroscopy (UV-vis DRS) were used to characterize the samples. It was found that tetragonal star-shaped Bi_5O_7Br crystals with high crystallinity could be obtained as pH value of the solution was about 9. Compared with flaky BiOBr particles, the star-shaped Bi_5O_7Br sample displayed red-shift in the UV-visible absorption edge, whereas the band gap was reduced to 2.57 eV and the specific surface area was increased. Among all samples, the star-shaped Bi_5O_7Br had the highest photocatalytic efficiency. After visible light irradiation for 10 min, the degradation rate of the rhodamine B (RhB) solution with a concentration of 10 mg·L~(-1) was almost 100%. Also, its photocatalytic activity was nearly unchanged after five cycles. It is believed that such Bi_5O_7Br could be used as stable and effective visible light catalysts.
机译:微米星形Bi_5O_7Br催化剂合成的Bi(NO_3)_3·5H_2O和十六烷基三甲基铵(CTAB)为原料,通过使用简单的水热法。 X射线衍射(XRD),扫描电子显微镜(SEM),高分辨率的透射电子显微镜(HRTEM),和紫外可见漫反射光谱(UV-VIS DRS)来表征样品。据发现,四方Bi_5O_7Br星形晶体具有高结晶可以作为溶液的pH值约为9。用片状BiOBr颗粒,Bi_5O_7Br星形样品显示在紫外 - 可见吸收边缘红移相比获得,而带隙降低到2.57 eV和比表面积增加。在所有样品中,星形Bi_5O_7Br具有最高的光催化效率。可见光照射10分钟后,用浓度为10mg若丹明B(罗丹明B)溶液的降解速率·L〜(-1)几乎为100%。此外,它的光催化活性是五个周期后,几乎没有变化。据认为,这种Bi_5O_7Br可以作为稳定和有效的可见光催化剂。

著录项

  • 来源
    《Journal of Materials Research》 |2021年第3期|628-636|共9页
  • 作者单位

    Guangxi Key Laboratory of Agricultural Resources Chemistry and Biotechnology College of Chemistry and Food Science Yulin Normal University Yulin 537000 Guangxi China;

    Guangxi Key Laboratory of Agricultural Resources Chemistry and Biotechnology College of Chemistry and Food Science Yulin Normal University Yulin 537000 Guangxi China;

    School of Materials Science and Engineering Jingdezhen Ceramic Institute Jingdezhen 333403 Jiangxi China;

    Guangxi Key Laboratory of Agricultural Resources Chemistry and Biotechnology College of Chemistry and Food Science Yulin Normal University Yulin 537000 Guangxi China;

    School of Materials Science and Engineering Jingdezhen Ceramic Institute Jingdezhen 333403 Jiangxi China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
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