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Enhanced power conversion efficiency of dye-sensitized solar cells with samarium doped TiO_2 photoanodes

机译:掺sa的TiO_2光阳极提高染料敏化太阳能电池的功率转换效率

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摘要

In this study, TiO_2 photoanodes doped with samarium ions via a method of hydrothermal treatment were used to fabricate dye-sensitized solar cells (DSSCs). Different doping concentrations were investigated on the effects of the cell's performance. Some techniques including XRD, scanning electron microscopy, HRTEM, XPS, UV-Vis, photoluminescence were used to characterize the morphology, structure, and optic properties of the prepared photoanodes. The photovoltaic performance of the fabricated cells was further evaluated by measuring the current density-voltage (J-V) curves. It was found that: (1) The down-conversion luminescence effect derived from samarium doping could enhance the light-harvesting ability. (2) Compared with the undoped sample, the samarium-doped cells exhibited enhanced photovoltaic performance. Among the cells with different doping concentrations, the cell TiO_2:0.015 Sm showed the best power conversion efficiency of 6.08% with a high open-circuit voltage (V_(oc)) and a short-circuit current density (J_(sc)).
机译:在这项研究中,通过水热处理方法掺入sa离子的TiO_2光阳极被用于制造染料敏化太阳能电池(DSSCs)。研究了不同掺杂浓度对电池性能的影响。一些技术包括XRD,扫描电子显微镜,HRTEM,XPS,UV-Vis,光致发光被用来表征制备的光阳极的形态,结构和光学性质。通过测量电流密度-电压(J-V)曲线进一步评估了制成电池的光伏性能。发现:(1)sa掺杂产生的降频转换发光效应可以增强光收集能力。 (2)与未掺杂样品相比,掺mar电池表现出增强的光伏性能。在具有不同掺杂浓度的电池中,具有高开路电压(V_(oc))和短路电流密度(J_(sc))的TiO_2:0.015 Sm电池表现出最佳的功率转换效率6.08%。

著录项

  • 来源
    《Journal of Materials Research》 |2017年第18期|3469-3476|共8页
  • 作者单位

    College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China;

    College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China;

    College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
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