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Visible Raman spectroscopy of carbon films synthesized by ion-plasma sputtering of graphite

机译:石墨的等离子溅射合成碳膜的可见拉曼光谱

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摘要

The article discusses the structure and properties of noncrystalline carbon films synthesized by ion-plasma sputtering of a graphite target in an argon atmosphere at direct current. Analysis of the molecular structure of carbon films was performed using Raman spectroscopy and dependence of the structure of synthesized films on the synthesis temperature and substrate material was revealed. Besides the main G peak possesses the values in a broad frequency range from 1500 to 1575 cm~(-1). The evolution of molecular structure peculiarities of synthesized carbon films depending on the synthesis conditions was clearly shown using the numerical methods of the Raman spectra decomposition. Studies of the optical spectra showed that the band gap of synthesized films varies from 0.78 to 1.67 eV and with increasing optical band gap, the value of G peak position decreases under laser excitation of 2.62 and 1.96 eV.
机译:本文讨论了在氩气气氛下直流电对石墨靶进行离子等离子溅射合成的非晶碳膜的结构和性能。使用拉曼光谱分析碳膜的分子结构,并揭示了合成膜的结构对合成温度和衬底材料的依赖性。除此以外,主G峰在1500至1575 cm〜(-1)的较宽频率范围内具有该值。使用拉曼光谱分解的数值方法清楚地显示了取决于合成条件的合成碳膜的分子结构特征的演变。光谱研究表明,合成薄膜的带隙在0.78至1.67 eV之间变化,并且随着光学带隙的增加,在2.62和1.96 eV的激光激发下,G峰位置的值减小。

著录项

  • 来源
    《Journal of Materials Research》 |2016年第1期|127-136|共10页
  • 作者单位

    National Nanotechnological Laboratory Open Type, Al-Farabi KazNU, Almaty 050012, Kazakhstan and Department of Molecular Physics, National Research Nuclear University MEPhI, Moscow 115409, Russia;

    National Nanotechnological Laboratory Open Type, Al-Farabi KazNU, Almaty 050012, Kazakhstan;

    National Nanotechnological Laboratory Open Type, Al-Farabi KazNU, Almaty 050012, Kazakhstan;

    National Nanotechnological Laboratory Open Type, Al-Farabi KazNU, Almaty 050012, Kazakhstan and Laboratory of engineering profile, Al-Farabi KazNU, Almaty 050040, Kazakhstan;

    National Nanotechnological Laboratory Open Type, Al-Farabi KazNU, Almaty 050012, Kazakhstan;

    Laboratory of engineering profile, Al-Farabi KazNU, Almaty 050040, Kazakhstan;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
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