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Microwave sintering of fine grained MgP and Mg substitutes with amorphous tricalcium phosphate: Structural, and mechanical characterization

机译:用无定形磷酸三钙微波烧结细粒MgP和Mg替代物:结构和机械特性

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摘要

This paper, for the first time, reports the results of microwave sintering of two emerging biomaterials, magnesium phosphate and amorphous magnesium calcium phosphate. Beneficial aspects of successful microwave sintering of calcium phosphate are well documented in the literature. The motivation for this work derives from the absence of any publication of similar nature on magnesium phosphates, which are becoming important with the rapid rise in interest in biodegradable Mg-alloys. Starting off with amorphous calcium magnesium phosphate and magnesium phosphate, the resulting microwave sintered product is a biphasic mixture of whitlockite substituted with magnesium and magnesium phosphate. The influence of the extent of Mg substitution on the mechanical properties, microstructure, and sintering behavior of tricalcium phosphate was evaluated. The results showed that the addition of Mg (up to the 50% wt/wt in relation to Ca mass) in the precursor compound of magnesium calcium phosphate improved the kinetics of the densification process and enhanced hardness values.
机译:本文首次报道了两种新兴生物材料-磷酸镁和无定形磷酸镁钙的微波烧结结果。磷酸钙的成功微波烧结的有益方面在文献中有充分的文献记载。开展这项工作的动机来自于没有任何类似性质的磷酸镁出版物,随着对可生物降解镁合金兴趣的迅速提高,磷酸镁变得越来越重要。从无定形的磷酸钙镁和磷酸镁开始,所得的微波烧结产物是被镁和磷酸镁取代的菱锰矿的两相混合物。评估了Mg取代程度对磷酸三钙的机械性能,微观结构和烧结行为的影响。结果表明,在磷酸钙镁的前体化合物中添加Mg(相对于Ca质量,至多为50%wt / wt)改善了致密化过程的动力学并提高了硬度值。

著录项

  • 来源
    《Journal of Materials Research》 |2016年第8期|995-1003|共9页
  • 作者单位

    Department of Bioengineering, University of Toledo, Toledo, Ohio 43606, USA;

    Department of Mechanical, Industrial and Manufacturing Engineering, University of Toledo, Toledo, Ohio 43606, USA;

    Department of Mechanical, Industrial and Manufacturing Engineering, University of Toledo, Toledo, Ohio 43606, USA Department of Surgery (Dentistry), University of Toledo, Toledo, Ohio 43614, USA;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
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