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Ultrafiltration performance and fouling resistance of PVB/SPES blend membranes with different degree of sulfonation

机译:不同磺化度的PVB / SPES共混膜的超滤性能和耐污性

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摘要

In the present study, we investigated the effects of different degree of sulfonation (DS) on the performance of the poly (vinyl butyral)/sulfonated polyethersulfone (PVB/SPES) blend membranes. The compatibility of the PVB/SPES blending system was characterized by shear viscosity and Fourier transform infrared attenuated total reflection, respectively. Results stated that all PVB/SPES blending systems were partially compatible. Contact angle, equilibrium water content, and x-ray photoelectron spectroscopy measurements were carried out to investigate the hydrophilicity of the PVB/SPES blend membranes. With increasing DS, the blend membranes became more hydrophilic. The pure water flux of the blend membranes increased with DS, while the rejection decreased due to microstructures of the PVB/SPES membranes. The mechanical properties of the PVB/SPES blend membranes increased slightly with DS. Fouling resistances of blend membranes evaluated by bovine serum albumin solution filtration revealed the PVB/SPES blend membranes with DS = 27% exhibited the superior antifouling properties.
机译:在本研究中,我们研究了不同磺化度(DS)对聚乙烯醇缩丁醛/磺化聚醚砜(PVB / SPES)共混膜性能的影响。 PVB / SPES混合系统的相容性分别由剪切粘度和傅立叶变换红外衰减的全反射来表征。结果表明,所有PVB / SPES混合系统都是部分兼容的。进行接触角,平衡水含量和X射线光电子能谱测量,以研究PVB / SPES共混膜的亲水性。随着DS的增加,共混膜变得更亲水。共混膜的纯水通量随DS的增加而增加,而拒收率则由于PVB / SPES膜的微结构而降低。 DS可使PVB / SPES共混膜的机械性能略有提高。通过牛血清白蛋白溶液过滤评估的共混膜的耐污垢性表明,DS = 27%的PVB / SPES共混膜表现出优异的防污性能。

著录项

  • 来源
    《Journal of Materials Research》 |2015年第18期|2688-2701|共14页
  • 作者单位

    College of Environmental Science and Engineering, Donghua University, Shanghai 201620, China;

    College of Environmental Science and Engineering, Donghua University, Shanghai 201620, China;

    College of Environmental Science and Engineering, Donghua University, Shanghai 201620, China;

    College of Environmental Science and Engineering, Donghua University, Shanghai 201620, China;

    College of Environmental Science and Engineering, Donghua University, Shanghai 201620, China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
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