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Silver-decorated ZnO hexagonal nanoplate arrays as SERS-active substrates: An experimental and simulation study

机译:银装饰的ZnO六角形纳米板阵列作为SERS活性基质:实验和模拟研究

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摘要

We have fabricated Ag-decorated ZnO nanoplate arrays by combining water-bath heating toward ZnO hexagonal nanoplate arrays and subsequent decoration of Ag films or nanoparticles on the ZnO surfaces by magnetron sputtering or photoreduction. Experimental surface-enhanced Raman scattering (SERS) results show that Ag-film-ZnO hybrid substrates with different Ag sputtering times exhibit a large difference in enhanced SERS signals for Rhodamine 6G (10~(-7) M). Atomic force microscope analysis reveals that two kinds of positions create abundant "hot spots" in this SERS substrate: one is located at the gap between adjacent separate Ag-film-ZnO hybrid nanoplates, and the other is located at the V-grooves formed by two adjacent interlaced Ag-film-ZnO hybrid nanoplates. The effects of simultaneous changes in interplate spacing and groove wall angle are considered to be the key factors affecting the SERS of our prepared Ag-film-ZnO hybrid substrates, which have also been evaluated by finite-difference time-domain simulation.
机译:我们通过将水浴加热到ZnO六角形纳米板阵列,然后通过磁控溅射或光还原在ZnO表面上装饰Ag膜或纳米颗粒,结合了Ag装饰的ZnO纳米板阵列。实验性表面增强拉曼散射(SERS)结果表明,具有不同Ag溅射时间的Ag-ZnO混合衬底在若丹明6G(10〜(-7)M)的增强SERS信号中表现出很大差异。原子力显微镜分析揭示了两种位置在此SERS衬底中产生大量“热点”:一种位于相邻的单独的Ag-ZnO / ZnO杂化纳米板之间的缝隙中,另一种位于由SERS衬底形成的V型槽中两个相邻的隔行扫描的银膜-ZnO杂化纳米板。板间间距和凹槽壁角的同时变化的影响被认为是影响我们所制备的Ag-膜-ZnO混合基板的SERS的关键因素,这些因素也已经通过有限差分时域仿真进行了评估。

著录项

  • 来源
    《Journal of Materials Research》 |2013年第24期|3374-3383|共10页
  • 作者单位

    Institute of Near-field Optics and Nanotechnology, School of Physics and Optoelectronic Technology, Dalian University of Technology, Ganjingzi District, Dalian 116024, People's Republic of China;

    Institute of Near-field Optics and Nanotechnology, School of Physics and Optoelectronic Technology, Dalian University of Technology, Ganjingzi District, Dalian 116024, People's Republic of China;

    Institute of Near-field Optics and Nanotechnology, School of Physics and Optoelectronic Technology, Dalian University of Technology, Ganjingzi District, Dalian 116024, People's Republic of China;

    Institute of Near-field Optics and Nanotechnology, School of Physics and Optoelectronic Technology, Dalian University of Technology, Ganjingzi District, Dalian 116024, People's Republic of China;

    Institute of Near-field Optics and Nanotechnology, School of Physics and Optoelectronic Technology, Dalian University of Technology, Ganjingzi District, Dalian 116024, People's Republic of China;

    Institute of Near-field Optics and Nanotechnology, School of Physics and Optoelectronic Technology, Dalian University of Technology, Ganjingzi District, Dalian 116024, People's Republic of China;

    Institute of Near-field Optics and Nanotechnology, School of Physics and Optoelectronic Technology, Dalian University of Technology, Ganjingzi District, Dalian 116024, People's Republic of China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
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  • 正文语种 eng
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