首页> 外文期刊>Journal of Materials Research >Low-temperature polymer precursor-based synthesis of nanocrystalline particles of lanthanum calcium manganese oxide (La_(0.67)Ca_(0.33)WnO_3) with enhanced ferromagnetic transition temperature
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Low-temperature polymer precursor-based synthesis of nanocrystalline particles of lanthanum calcium manganese oxide (La_(0.67)Ca_(0.33)WnO_3) with enhanced ferromagnetic transition temperature

机译:铁磁转变温度提高的低温聚合物前驱体基合成镧钙锰氧化物(La_(0.67)Ca_(0.33)WnO_3)纳米晶体颗粒的方法

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摘要

We report a simple modified polymeric precursor route for the synthesis of highly crystalline and homogenous nanoparticles of lanthanum calcium manganese oxide (LCMO). The LCMO phase formation was studied by thermal analysis, x-ray powder diffraction, and infrared spectroscopy at different stages of heating. These nanocrystallites (average particle size of 30 nm) possess ferromagnetic-paramagnetic transition temperature (T_c) of 300 K, nearly 50 K higher than that of a single crystal. The Rietveld analysis of the powder x-ray diffraction data of the nanopowders reveals significant lattice contraction and reduction in unit cell anisotropy-these structural changes are correlated to the enhancement in T_c.
机译:我们报告了一种简单的改性聚合物前体路线,用于合成镧钙锰氧化物(LCMO)的高结晶度和均质纳米颗粒。在加热的不同阶段,通过热分析,X射线粉末衍射和红外光谱研究了LCMO相的形成。这些纳米晶体(平均粒径为30 nm)具有300 K的铁磁-顺磁转变温度(T_c),比单晶高近50K。纳米粉末的粉末X射线衍射数据的Rietveld分析显示出明显的晶格收缩和晶胞各向异性的降低-这些结构变化与T_c的提高有关。

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