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Facile route to tin oxide containing mesoporous silica composites with room-temperature photoluminescence

机译:具有室温光致发光特性的含氧化锡的介孔二氧化硅复合材料的简便方法

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摘要

In this paper, we report a facile route, the tin vapor treatment method, to prepare tin oxide containing mesoporous silica composites (TOMS), which display room-temperature photoluminescence (RT-PL). Among them, TOMS-1 and TOMS-2 were synthesized from mesoporous silica SBA-15 and KIT-6, respectively. They are composed of amorphous SiO_2 and tin oxide species and they display strong emission near ultraviolet (UV) when excited by UV light. By increasing the preparation temperature, their Sn content can be increased and subsequently their photoluminescence (PL) intensities can be greatly enhanced. Besides, their PL properties are revealed to be closely related to 2-fold-coordinated tin oxygen-deficient centers.
机译:在本文中,我们报告了一种简便的途径,即锡蒸气处理方法,以制备含有中孔二氧化硅复合材料(TOMS)的氧化锡,该复合材料具有室温光致发光(RT-PL)的特性。其中,TOMS-1和TOMS-2分别由中孔二氧化硅SBA-15和KIT-6合成。它们由无定形的SiO_2和氧化锡组成,当被紫外线激发时,它们在紫外线(UV)附近显示强发射。通过提高制备温度,可以增加其Sn含量,随后可以大大提高其光致发光(PL)强度。此外,它们的PL性质被揭示与2倍配位的锡缺氧中心密切相关。

著录项

  • 来源
    《Journal of Materials Research》 |2006年第3期|p.655-663|共9页
  • 作者单位

    State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, People's Republic of China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 工程材料学;
  • 关键词

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