首页> 外文期刊>Journal of Materials Research >Dielectric and piezoelectric properties of niobium-modified BiINO3-PbTiO3 perovskite ceramics with high Curie temperatures
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Dielectric and piezoelectric properties of niobium-modified BiINO3-PbTiO3 perovskite ceramics with high Curie temperatures

机译:居里温度高的铌改性BiINO3-PbTiO3钙钛矿陶瓷的介电和压电性能

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摘要

Piezoelectric ceramics with T-c > 500 degrees C were projected in the perovskite BiInO3-PbTiO3 (BIPT) system based on their low tolerance factor (similar to 0.884). However, a stable perovskite phase could be synthesized only when the PbTiO3 (PT) content was greater than 75%. Furthermore, the large tetragonality (c/a > 1.08) and low electrical resistivity made the ceramics difficult to pole. Niobium-modified BIPT ceramics with PT contents of 80% and 85% were found to possess significantly lower dielectric loss at elevated temperatures, making it possible to polarize the materials. Piezoelectric properties were measured for a BIPT85-1.5 mol% Nb composition with a Curie temperature of 542 degrees C; the longitudinal piezoelectric coefficient and coercive field were found to be 60 pC/N and 125 kV/cm, respectively.
机译:钙钛矿型BiInO3-PbTiO3(BIPT)系统基于其低容忍度(类似于0.884),投影了T-c> 500摄氏度的压电陶瓷。但是,只有当PbTiO3(PT)含量大于75%时,才能合成稳定的钙钛矿相。此外,大的四方性(c / a> 1.08)和低电阻率使陶瓷难以极化。发现PT含量为80%和85%的铌改性BIPT陶瓷在高温下具有明显更低的介电损耗,从而可以使材料极化。对于居里温度为542℃的BIPT85-1.5mol%Nb组合物,测量了压电性能。纵向压电系数和矫顽场分别为60 pC / N和125 kV / cm。

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