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Ordering in (La,Sr)(Al,Ta)O_3 substrates

机译:在(La,Sr)(Al,Ta)O_3基板中订购

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摘要

(La, Sr)(Al, Ta)O_3 (LSAT) has recently received increased attention as a substrate for the deposition of various oxide films. LSAT is usually considered as having a perovskite structure. However, the exact atomic structure of LSAT is not yet well known and has received little attention up to now. In this paper, a series of studies using x-ray diffraction, transmission electron microscopy, and energy dispersive spectrometry were conducted to determine the atomic structure of LSAT. It was found that LSAT consists of two types of domains: one with a simple cubic perovskite structure (disordered with a = 0.3868 nm) and the other with a face-centered-cubic structure (ordered with a = 0.773 nm). Computer image simulation of high-resolution lattice images suggests that the ordered structure is due to ordering of the Al and Ta ions.
机译:作为沉积各种氧化物膜的衬底,(La,Sr)(Al,Ta)O 3(LSAT)最近受到越来越多的关注。 LSAT通常被认为具有钙钛矿结构。然而,LSAT的确切原子结构尚不为人所知,到目前为止还很少受到关注。在本文中,使用X射线衍射,透射电子显微镜和能量色散光谱进行了一系列研究,以确定LSAT的原子结构。已发现,LSAT由两种类型的畴组成:一种具有简单的立方钙钛矿结构(无序= 0.3868 nm),另一种具有面心立方结构(无序= 0.773 nm)。高分辨率晶格图像的计算机图像模拟表明,有序结构归因于Al和Ta离子的有序性。

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