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The use of polymeric milling media in the reduction of contamination during mechanical attrition

机译:使用聚合物研磨介质减少机械磨损过程中的污染

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Aluminum samples were milled in a high-energy ball mill at times ranging from 10 to 500 min in stainless vial/media and nylon vial/media. The crystallite size of aluminum milled in the stainless steel setup reached a plateau at 25 nm around 100 min, whereas the crystallite size of aluminum milled in the nylon setup reached the same plateau at 500 min. Contamination studies were conducted using x-ray fluorescence, hydrogen―carbon―nitrogen analysis, and thermogravimetric analysis. Although organic contamination due to the nylon milling media was high at 12 wt% when milled for 500 min, it is shown that the contaminant could be easily removed by thermal treatment.
机译:铝样品在高能球磨机中在10到500分钟的时间内在不锈钢小瓶/介质和尼龙小瓶/介质中研磨。在不锈钢装置中研磨的铝的微晶尺寸在100分钟左右达到25 nm的平稳期,而在尼龙装置中研磨的铝的微晶尺寸在500分钟时达到相同的平稳期。使用X射线荧光,氢-碳-氮分析和热重分析进行污染研究。尽管当研磨500分钟时,尼龙研磨介质导致的有机污染物含量高达12 wt%,但表明该污染物可以通过热处理轻松去除。

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