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Poly(meta-phenylene isophthalamide) nanofibers: Coating and post processing

机译:聚(间亚苯基间苯二甲酰胺)纳米纤维:涂层和后处理

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摘要

Electrospun nanofibers have applications in the areas of filtration, composites, biomaterials, and electronics. Controlling the surface properties of these nanofibers is important for many applications. Nanofibers can also be used as unique substrates for observing the growth of deposited films and creating nanoscale structures. In this work, electrospun poly(meta-phenylene isophthalamide) (MPD-I) nanofibers were used as substrates for creating nanoscale structures out of carbon-based materials and metals. MPD-I was used because it can be electrospun into nanofibers with diameters smaller than 10 nm and it has good thermal stability. MPD-I nanofibers were coated with carbon, copper, and aluminum using plasma enhanced chemical vapor deposition and physical vapor deposition methods. Some of the aluminum-coated nanofibers were then converted into nanotubes. Transmission electron microscopy was used to determine the thickness, uniformity, and grain size of the coatings on the fibers and the nanotubes.
机译:电纺纳米纤维在过滤,复合材料,生物材料和电子学领域具有应用。对于许多应用而言,控制这些纳米纤维的表面性质很重要。纳米纤维还可以用作观察沉积膜生长和形成纳米级结构的独特基材。在这项工作中,静电纺丝的聚(间亚苯基间苯二甲酰胺)(MPD-1)纳米纤维被用作从碳基材料和金属中创建纳米级结构的基质。使用MPD-1是因为它可以电纺成直径小于10 nm的纳米纤维,并且具有良好的热稳定性。使用等离子增强化学气相沉积和物理气相沉积方法,用碳,铜和铝涂覆MPD-1纳米纤维。然后将一些铝包覆的纳米纤维转化为纳米管。使用透射电子显微镜确定纤维和纳米管上涂层的厚度,均匀性和晶粒尺寸。

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