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Effect of recrystallization on the oxidative stability of poly(butylene terephthalate)

机译:重结晶对聚对苯二甲酸丁二醇酯氧化稳定性的影响

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摘要

The oxidative stability of poly(butylene terephthalate) was investigated over the range l75 to 220 deg C by isothermal differential calorimetry. It is shown that this property is affected by a fast recrystallization process, which takes place between 200 and 220 deg C, with a maximum around 208 deg C. In fact, recrystallization produces an increase of the crystallinity degree of the polymer, which enhances its resistance to oxidation, as proven by the longer oxidation times detected.
机译:通过等温差热法研究了聚对苯二甲酸丁二酯在175到220摄氏度范围内的氧化稳定性。结果表明,该性能受到快速重结晶过程的影响,该过程发生在200到220摄氏度之间,最大值在208摄氏度左右。事实上,重结晶会增加聚合物的结晶度,从而提高聚合物的结晶度。更长的氧化时间证明了其抗氧化性。

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