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首页> 外文期刊>Journal of Materials Research >Fracture modes in brittle coatings with large interlayer modulus mismatch
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Fracture modes in brittle coatings with large interlayer modulus mismatch

机译:层间模量不匹配大的脆性涂层的断裂模式

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Fracture modes in a model glass--polymer coating--substrate system indented with hard spheres are investigated. The large modulus mismatch between the glass and polymer results in distinctive transverse fracture modes within the brittle coating f exaggerated circumferential (C) ring cracks that initiate at the upper coating surface well outside the contact (as opposed to the near-contact Heltzian cone fractures observed in monolithic brittle materials); median-radial (M) cracks that initiate at the lower surface (i.e., at the substrate interface) on median planes containing the contact axis. Bonding between the coating and substrate is sufficiently strong as to preclude delamination in our system. The transparency of the constituent materials usefully enables in situ identification and quantification of the two transverse fracture modes during contact. The morphologies of the cracks and the corresponding critical indentation loads for initiation are measured over a broad range of coating thicknesses (20 pm to 5.6 mm), on coatings with like surface flaw states, here ensured by a prebonding abrasion treatment. There is a well-defined, broad intermediate range where the indented coating responds more like a flexing plate than a Hertzian contact, and where the M and C cracks initiate in close correspondence with a simple critical stress criterion, i.e., when the maximum tensile stresses exceed the bulk strength of the (abraded) glass. In this intermediate range the M cracks generally form first--Only when the flaws on the lower surface are removed (by etching) do the C cracks f
机译:研究了带有硬球的模型玻璃-聚合物涂层-基底系统中的断裂模式。玻璃和聚合物之间的大模量不匹配会导致脆性涂层内出现明显的横向断裂模式,而在接触之外的上涂层表面处开始出现夸张的周向(C)环裂纹(与观察到的近接触赫兹锥裂相反)在整体脆性材料中);在包含接触轴的中间平面的下表面(即在基材界面处)起始的中间径向(M)裂纹。涂层和基材之间的结合足够牢固,可以防止我们系统中的分层。组成材料的透明性使接触过程中两个横向断裂模式的原位识别和定量化成为可能。在具有类似表面缺陷状态的涂层上,通过预粘结磨损处理确保了裂纹的形态和相应的引发临界压痕载荷,该涂层的涂层厚度范围很广(20 pm至5.6 mm)。有一个明确的,宽泛的中间范围,其中凹进的涂层比赫兹接触更像挠性板,并且M和C裂纹的产生与简单的临界应力准则(即最大拉应力)密切相关超过(磨光)玻璃的体积强度。在这个中间范围内,通常会先形成M个裂纹-只有当下表面的缺陷被去除(通过蚀刻)时,C裂纹才会形成

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