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Advancement on suppression of energy dissipation of percolative polymer nanocomposites: a review on graphene based

机译:抑制渗流聚合物纳米复合材料能量耗散的研究进展:基于石墨烯的研究进展

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摘要

Percolative polymer nanocomposites (PPNC) such as polymers reinforced with graphene and/or carbon nanotubes have attracted research attention on the effort to improve the energy storage capacity of polymeric materials. Such nanocomposites often associated with high energy dissipation and dielectric loss. Recently, research interests have shifted from increasing dielectric constant of PPNC to the reduction of dielectric loss associated with such nanocomposites. Various means have been employed in the suppression of energy dissipation and dielectric loss of PPNC via covalent and non-covalent modification of percolative nanofillers (PnF). For instance, chemical and mechanical (physical) techniques of insulating PnF have been employed in the reduction of current leakage, high mobility of charge carriers and direct contact of PnF in the polymer matrix. A significant reduction in the energy dissipation of PPNC has been achieved so far. However, there is still a need for further reduction of energy dissipation associated with such nanocomposites to realize their practical applications as dielectric energy storage materials. Therefore, this review summarised the various techniques employed by various studies in the reduction of energy dissipation associated with PPNC and results achieved using the techniques. The review was concluded with present challenges and the way forward to further address the challenges facing PPNC as dielectric energy storage materials.
机译:渗透性聚合物纳米复合材料(PPNC),例如用石墨烯和/或碳纳米管增强的聚合物,已引起人们对提高聚合物材料储能能力的研究关注。此类纳米复合材料通常与高能量耗散和介电损耗有关。近来,研究兴趣已从增加PPNC的介电常数转向减少与此类纳米复合材料相关的介电损耗。通过渗透性纳米填料(PnF)的共价和非共价修饰,已采用各种手段抑制PPNC的能量耗散和介电损耗。例如,绝缘PnF的化学和机械(物理)技术已被用于减少电流泄漏,电荷载流子的高迁移率以及PnF在聚合物基质中的直接接触。迄今为止,已经大大降低了PPNC的能耗。然而,仍然需要进一步减少与此类纳米复合材料相关的能量耗散,以实现其作为介电储能材料的实际应用。因此,本综述总结了各种研究在减少与PPNC相关的能量耗散方面所采用的各种技术,以及使用该技术获得的结果。审查结束时提出了当前的挑战以及进一步解决PPNC作为介电储能材料所面临的挑战的方法。

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  • 来源
    《Journal of materials science》 |2019年第18期|16966-16982|共17页
  • 作者单位

    Tshwane Univ Technol Dept Chem Met & Mat Engn Private Bag X680 Pretoria South Africa;

    Tshwane Univ Technol Dept Elect Engn Private Bag X680 Pretoria South Africa;

    Tshwane Univ Technol Dept Chem Met & Mat Engn Private Bag X680 Pretoria South Africa|Univ Nigeria Dept Met & Mat Engn Private Bag 0004 Nsukka Enugu Nigeria;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
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