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Redox properties of a green emitting ZnGa_(2)O_(4):Mn low voltage cathodoluminescent phosphor

机译:绿光发射ZnGa_(2)O_(4):Mn低压阴极荧光粉的氧化还原特性

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The emission properties of ZnGa_(2)O_(4):Mn phosphors have been compared for samples prepared via an oxalate gel route and those prepared via a conventional solid synthetic route. The firing conditions were found to be critical for obtaining good emission on account of possible redox processes involving both the Mn~(2+) activator ion and the host ZnGa_(2)O_(4) lattice itself. An interesting reversible shift was observed for the CIE coordinates of the cathodo-luminescence when the energy of the exciting electron beam was varied. This is explained by increased vibronic excitation of the ZnGa_(2)O_(4):Mn phosphors at higher electron beam energies, resulting in a greater relative contribution of the vibronic side bands to the green emission.
机译:ZnGa_(2)O_(4):Mn磷光体的发射性能已通过草酸盐凝胶途径制备的样品与常规固体合成途径制备的样品进行了比较。由于涉及到Mn〜(2+)活化剂离子和主体ZnGa_(2)O_(4)晶格本身的可能的氧化还原过程,发现焙烧条件对于获得良好的发射是至关重要的。当激发电子束的能量发生变化时,阴极发光的CIE坐标观察到一个有趣的可逆位移。 ZnGa_(2)O_(4):Mn磷光体在更高的电子束能量下增加的电子振动激发可以解释这一点,从而导致电子振动边带对绿色发射的相对贡献更大。

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