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首页> 外文期刊>Journal of Materials Science >Synthesis, photoluminescence and mechanoluminescence properties of Eu3+ ions activated Ca2Gd2W3O14 phosphors
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Synthesis, photoluminescence and mechanoluminescence properties of Eu3+ ions activated Ca2Gd2W3O14 phosphors

机译:Eu3 + 离子激活的Ca2 Gd2 W3 O14 荧光粉的合成,光致发光和机械致发光性质

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摘要

A new series of Eu3+ ions-activated calcium gadolinium tungstate [Ca2Gd2W3O14] phosphors were synthesized by conventional solid-state reaction method. The X-ray diffraction patterns of the powder samples indicate that the Eu3+: Ca2Gd2W3O14 phosphors are of tetragonal structure. The prepared phosphors were well characterized by scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDAX), Fourier transform infrared spectroscopy (FTIR), photoluminescence (PL), and mechanoluminescence (ML) spectra. PL spectra of Eu3+: Ca2Gd2W3O14 powder phosphors have shown strong red emission at 615 nm (5D0 → 7F2) with an excitation wavelength λ exci = 392 nm (7F0 → 5L6). The energy transfer from tungstate groups to europium ions has also reported. Mechanoluminescence studies of Eu3+: Ca2Gd2W3O14 phosphors have also been explained systematically.
机译:通过常规固相反应法合成了一系列新的Eu3 +离子活化的钨酸钙g钙[Ca2 Gd2 W3 O14 ]荧光粉。粉末样品的X射线衍射图谱表明,Eu3 + :Ca2 Gd2 W3 O14 荧光粉具有四方结构。制备的荧光粉通过扫描电子显微镜(SEM),能量色散X射线分析(EDAX),傅立叶变换红外光谱(FTIR),光致发光(PL)和机械发光(ML)光谱得到了很好的表征。 Eu3 + :Ca2 Gd2 W3 O14 粉末荧光粉的PL光谱在615 nm(5 D0 →7 F2 )的激发波长λexci = 392 nm(7 F0 →5 L6 )。从钨酸盐集团到euro离子的能量转移也有报道。还系统地解释了Eu3 + :Ca2 Gd2 W3 O14 磷光体的机械发光研究。

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