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首页> 外文期刊>Journal of Materials Science >Preparation, characterization and conductivity studies of AgI-Ag2O-(TeO2 + P2O5) fast ionic conducting glasses
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Preparation, characterization and conductivity studies of AgI-Ag2O-(TeO2 + P2O5) fast ionic conducting glasses

机译:AgI-Ag2 O-(TeO2 + P2 O5 )快速离子导电玻璃的制备,表征和电导率研究

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摘要

Silverphosphotellurate (SPT) quaternary fast ionic conducting (FIC) glasses of compositions AgI-Ag2O-[(1 − x)P2O5 + xTeO2], x = 0.0 to 1.0 in steps of 0.1, were prepared by melt quenching. All SPT compounds were characterized by X-ray diffraction and the amorphous nature of the samples was confirmed. The structure of all compositions was examined by Fourier Transform Infrared Spectroscopy. The glass transition temperature (T g) was determined for all SPT samples, using differential scanning calorimetry. Complex impedance measurements were made on all glasses in the frequency range 40 Hz to 100 kHz. Impedance data were analyzed using Boukamp equivalent circuit software and the bulk conductivity was obtained. The highest conductivity (σ = 1.59*10−2 S/cm) was shown by the composition 60%AgI − 26.67%Ag2O − 13.33% (0.3P2O5 + 0.7TeO2).
机译:组成为AgI-Ag2 O-[(1-x)P2 O5 + xTeO2 ]的成分的磷酸二氢银(SPT)季快速离子导电(FIC)玻璃,x = 0.0通过熔融淬火制备以0.1为步长至1.0至1.0。所有SPT化合物均通过X射线衍射表征,并确认了样品的无定形性质。通过傅立叶变换红外光谱法检查所有组合物的结构。使用差示扫描量热法测定所有SPT样品的玻璃化转变温度(T g )。在所有玻璃上,在40 Hz至100 kHz的频率范围内进行复数阻抗测量。使用Boukamp等效电路软件分析阻抗数据,并获得体电导率。 60%AgI-26.67%Ag2 O-13.33%(0.3P2 O5 表示最高电导率(σ= 1.59 * 10-2 S / cm) > + 0.7TeO2 )。

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