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Obtaining Ultra-High Surface Area TiO_2 Nanorods via Hydrothermally Transformation of Elongated Titanate Nanotubes

机译:通过水热转化伸长的钛酸酯纳米管获得超高表面积的TiO_2纳米棒。

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摘要

In this paper, a tunable TiO2 nanorod cross-link structure with ultra-high surface area (up to 109.81 m(2)/g) has been successfully prepared via hydrothermally treating elongated sodium titanate nanotubes. XRD, SEM, HRTEM and BET analysis were employed to characterize the morphology and inner structure of the samples. The preparation conditions (the hydrothermal temperatures and the pH values of the solutions) of the obtained TiO2 products were systematically studied. The maximum length of nanorod reaches to 1 mu m while the lateral size could be limited less than 10 nm. The surface area can be easily tuned by modifying the stirring rate during the hydrothermal process. In addition, the photocatalytic performance of synthesized TiO2 nanorods were also measured, and the nanorod structure with ultra-high surface area showed much better photocatalytic activity than the sample produced without stirring process, which can be attributed to the influence of the large difference in specific surface area of the obtained TiO2 products.
机译:在本文中,通过水热处理细长的钛酸钠纳米管成功地制备了具有超高表面积(高达109.81 m(2)/ g)的可调式TiO2纳米棒交联结构。利用XRD,SEM,HRTEM和BET分析来表征样品的形貌和内部结构。系统地研究了所得TiO2产物的制备条件(水热温度和溶液的pH值)。纳米棒的最大长度达到1微米,而横向尺寸可以限制为小于10纳米。通过改变水热过程中的搅拌速率可以容易地调节表面积。此外,还测量了合成的TiO2纳米棒的光催化性能,具有超高表面积的纳米棒结构比未经搅拌的样品显示出更好的光催化活性,这可归因于比表面积差异大的影响。所获得的TiO 2产物的表面积。

著录项

  • 来源
    《Journal of nano research》 |2018年第2018期|13-23|共11页
  • 作者单位

    Hubei Univ Technol, Hubei Collaborat Innovat Ctr High Efficiency Util, Wuhan 430068, Hubei, Peoples R China;

    Hubei Univ Technol, Sch Chem & Chem Engn, Wuhan 430068, Hubei, Peoples R China;

    Hubei Univ Technol, Sch Chem & Chem Engn, Wuhan 430068, Hubei, Peoples R China;

    Hubei Univ Technol, Sch Chem & Chem Engn, Wuhan 430068, Hubei, Peoples R China;

    Hubei Univ Technol, Sch Chem & Chem Engn, Wuhan 430068, Hubei, Peoples R China;

    Hubei Univ Technol, Sch Chem & Chem Engn, Wuhan 430068, Hubei, Peoples R China;

    Hubei Univ Technol, Hubei Collaborat Innovat Ctr High Efficiency Util, Wuhan 430068, Hubei, Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    TiO2 nanorods; Stirring hydrothermal approach; High surface area; Photocatalytic activity;

    机译:TiO2纳米棒;搅拌水热法;高比表面积;光催化活性;

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