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Scalable Synthesis of Ultrathin g-C3N4 Nanosheets with Enhanced Photocatalytic Activities via High Shear Exfoliation

机译:通过高剪切剥离可扩展合成具有增强的光催化活性的超薄g-C3N4纳米片

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摘要

High-shear mixing was demonstrated as an effective approach for the green synthesis of ultrathin g-C3N4 nanosheets with excellent photocatalytic performance. The resultant nanosheets were characterized in terms of morphology, crystal structure, electronic structure and photocatalytic behavior. It was found that the g-C3N4 nanosheets mainly consist of one C-N layer with a thickness about 0.7 nm. The products show a band gap of 2.6 eV and exhibit high photocatalytic activities with almost 4 times higher than their bulk counterparts toward RhB degradation. With the yield as high as 20 %, the present simple route may be qualified as a promising candidate for the mass production of high quality g-C3N4 nanosheets.
机译:高剪切混合被证明是绿色合成具有优异光催化性能的超薄g-C3N4纳米片的有效方法。所得纳米片材在形态,晶体结构,电子结构和光催化行为方面进行了表征。发现g-C3N4纳米片主要由厚度约为0.7nm的一个C-N层组成。该产品的带隙为2.6 eV,并具有较高的光催化活性,对RhB的降解几乎是其同类产品的4倍。由于产率高达20%,因此本简单路线可被认为是大规模生产高质量g-C3N4纳米片的有希望的候选者。

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