Novel Formulation of the Gibbs-Energy Change in Terms of Stoichiometrically Unique Response Reactions

Ilie Fishtik; Istvan Nagypal; Ivan Gutman

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Novel Formulation of the Gibbs-Energy Change in Terms of Stoichiometrically Unique Response Reactions

机译：基于化学计量唯一反应的吉布斯能量变化的新颖表达

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The equation for the change of Gibbs energy in complex chemical systems is reformulated in terms of the newly conceived response reactions (RERs). The present formulation has the remarkable property of being unique: the composition of the species unequivocally determines the response reactions and via them the change of the Gibbs energy of the system. Furthermore, it enables one to reinterpret and rationalize some basic concepts of chemical thermodynamics, as coupling between reactions, sensitivity coefficients, etc.

机译：吉布斯能量在复杂化学系统中的变化方程式是根据新构想的反应（RER）重新公式化的。本配方具有独特的显着特性：该物种的组成明确确定了响应反应，并通过它们确定了系统的吉布斯能量的变化。此外，它使人们能够重新解释和合理化化学热力学的一些基本概念，如反应之间的耦合，灵敏度系数等。

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《Zeitschrift fur Naturforschung. A, A journal of physical sciences》 |1996年第11期|p.1079-1083|共5页
作者
Ilie Fishtik; Istvan Nagypal; Ivan Gutman;
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正文语种 eng
中图分类物理学;
关键词
chemical thermodynamics; sensitivity analysis; response reactions; thermodynamic coupling (of chemical reactions);

机译：化学热力学;灵敏度分析;响应反应;（化学反应的）热力学耦合;

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Novel Formulation of the Gibbs-Energy Change in Terms of Stoichiometrically Unique Response Reactions

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