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Removal Of Endosulfan From Water Using Oil Palm Shell Activated Carbon And Rice Husk Ash

机译:使用油棕壳活性炭和稻壳灰从水中去除硫丹

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In this study, the adsorption of endosulfan, a type of pesticide, onto agricultural waste-based adsorbents, namely, oil palm shell activated carbon (PSAC) and rice husk ash (RHA), was investigated. The as-received adsorbents were used for batch a- and β-endosulfan adsorption studies which included kinetics and equilibrium aspects at a constant solution pH of 5 and at a temperature of 25℃. It was found that removal of β-endosulfan by both adsorbents was significantly more efficient than that of α-endosulfan indicating a high affinity of PSAC and RHA towards β-endosulfan. Interestingly, kinetic equilibrium for β-endosulfan adsorption onto PSAC was achieved after 30 min of contact time with a very high capacity of 418 mg g~(-1). The adsorption kinetics data fitted the pseudo-second order model well, implying chemisorption was the rate-controlling step. Equilibrium adsorption data for PSAC fit the Freundlich isotherm better than the Langmuir isotherm, suggesting the existence of multi-layer adsorption of endosulfan on a relatively heterogeneous PSAC surface. It was found that PSAC was efficient in removing β-endosulfan from water while it was conversely true for RHA.
机译:在这项研究中,研究了硫丹(一种农药)在农业废弃物基吸附剂(油棕壳活性炭(PSAC)和稻壳灰(RHA))上的吸附。按原样使用吸附剂进行α-硫丹和β-硫丹的批量吸附研究,其中包括在恒定溶液pH 5和温度25℃下的动力学和平衡方面的研究。发现两种吸附剂去除β-硫丹的效率明显高于α-硫丹,这表明PSAC和RHA对β-硫丹的亲和力高。有趣的是,在接触30分钟后,β-硫丹吸附到PSAC上的动力学平衡达到了418 mg g〜(-1)的极高容量。吸附动力学数据很好地拟合了拟二级模型,表明化学吸附是速率控制步骤。 PSAC的平衡吸附数据比Langmuir等温线更适合Freundlich等温线,表明硫丹在相对异质的PSAC表面上存在多层吸附。发现PSAC​​可有效地从水中去除β-硫丹,而对于RHA则相反。

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