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Competition between Lorentzian Gaussian width in pure oxygen absorption spectrum at 1264 nm band

机译:1264 nm波段纯氧吸收光谱中的洛伦兹高斯宽度之间的竞争

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摘要

Voigt deconvolution method was applied to analyze experimental pure oxygen absorption spectrum at 1270 nm band. This method gives two bands, the first is a weak discrete absorption band at 1268 nm and vanishes under high pressures, whereas the second is a continuous absorption band at 1264 nm and prevails under high pressures. Applicable pressures were varied between 10 and 25 bar, and temperatures at 298, 323, 348, and 373 K. Competition between pressure broadening and Doppler broadening was very sensitive. Gaussian width, Lorentzian width, and Voigt full width at half-maximum height (Voigt FWHM) were calculated for each spectral line.
机译:Voigt反褶积法用于分析1270 nm波段的实验纯氧吸收光谱。该方法给出了两个谱带,第一个是在1268nm处的弱离散吸收带,在高压下消失,而第二个是在1264nm处的连续吸收带,并在高压下普遍存在。适用压力在10至25 bar之间变化,温度分别为298、323、348和373 K.压力展宽和多普勒展宽之间的竞争非常敏感。计算每个谱线的高斯宽度,洛伦兹宽度和半最大高度的Voigt全宽度(Voigt FWHM)。

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