Catalytic oxidation of alkylbenzenes with molecular oxygen under normal pressure and temperature by N-hydroxyphthalimide combined with Co(Oac)

Yasushi Yoshino; Yoshiaki Hayashi; Takahiro Iwahama

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Catalytic oxidation of alkylbenzenes with molecular oxygen under normal pressure and temperature by N-hydroxyphthalimide combined with Co(Oac)

机译：N-羟基邻苯二甲酰亚胺与Co（Oac）组合在常压常温下用分子氧催化烷基苯氧化

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A practical catalytic method to convert alkylbenzenes into the corresponding carboxylic acids under atmospheric dioxygen at ambient temperature using a combined catalytic system consisting of N-hydroxyphthalimide (NHPI) and CO(Oac)_2 was developed. For instance, the oxidation of toluene Was completed by NHPI combined with Co(Oac)_2 under an oxygen atmosphere at room temperature To give benzoic acid in 81/100 yield.

机译：开发了一种实用的催化方法，该方法是在环境温度下，使用由N-羟基邻苯二甲酰亚胺（NHPI）和CO（Oac）_2组成的联合催化体系，在大气压双氧下将烷基苯转化为相应的羧酸。例如，甲苯的氧化是通过在室温下的氧气气氛下，将NHPI与Co（Oac）_2结合而完成的，从而以81/100的收率得到苯甲酸。

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《The Journal of Organic Chemistry》 |1997年第20期|p.6810-6813|共4页
作者
Yasushi Yoshino; Yoshiaki Hayashi; Takahiro Iwahama;
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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种 eng
中图分类有机化学;
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1. ALKANE OXIDATION WITH MOLECULAR OXYGEN USING A NEW EFFICIENT CATALYTIC SYSTEM - N-HYDROXYPHTHALIMIDE (NHPI) COMBINED WITH CO(ACAC)(N) (N=2 OR 3) [J] . Ishii Y., Sakaguchi S., Nakayama K., The Journal of Organic Chemistry . 1996,第14期

机译：使用新型高效催化系统-羟基邻苯二甲酰亚胺（NHPI）与CO（ACAC）（N）结合（N = 2或3）用分子氧氧化烷烃
2. Facile oxidative cleavage of benzylidene acetals using molecular oxygen catalyzed by N-hydroxyphthalimide/Co(OAc)_2 [J] . Yongsheng Chen, Peng George Wang Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2001,第30期

机译：N-羟基邻苯二甲酰亚胺/ Co（OAc）_2催化的分子氧对亚苄基乙缩醛的氧化裂解作用
3. Catalytic properties of N-hydroxyphthalimide immobilized on a novel porous organic polymer in the oxidation of toluene by molecular oxygen [J] . Meng Jian, Cui Jianlan, Luo Dongmei, RSC Advances . 2016,第72期

机译：用分子氧对新型多孔有机聚合物固定在新型多孔有机聚合物上的N-羟基苯二甲酰亚胺的催化性质
4. Selective oxidation of ethylbenzene catalyzed by N-hydroxyphthalimide (NHPI) and ZSM-5 supported Co(II), Mn(II), Cu(II), Zn(II), Fe(III) with molecular oxygen under mild conditions (PPT) [C] . Lei Chen, Bindong Li, Dabin Li AIChE Annual Meeting . 2014

机译：在温和条件下用分子氧（PPT）的N-羟基苯二甲酰亚胺（NHPI）和ZSM-5负载的CO（II），Mn（II），Cu（III），Zn（II），Fe（III），Mn（II），Fe（III）催化的选择性氧化氧化
5. HETEROGENEOUS CATALYTIC HYDRODEOXYGENATION OF CRESOLS (METHYL PHENOLS) ON SULFIDED COBALT-OXIDE - MOLYBDENUM-TRIOXIDE/GAMMA-ALUMINA-OXIDE CATALYSTS AT HIGH TEMPERATURES AND PRESSURES [D] . ODEBUNMI, EZEKIEL OLUYEMI 1982

机译：高温高压下硫化钴-三氧化钼/γ-氧化铝-异氰酸酯催化剂上异戊二烯（甲基苯酚）的催化加氢
6. Effects of time delay and body temperature on measurements of central venous oxygen saturation venous-arterial blood carbon dioxide partial pressures difference venous-arterial blood carbon dioxide partial pressures difference/arterial-venous oxygen difference ratio and lactate [O] . Xiang-yu Wan, Li-li Wei, Yan Jiang, 2018

机译：时间和体温对中心静脉血氧饱和度静脉-动脉血二氧化碳分压差静脉-动脉血二氧化碳分压差/动脉-静脉血氧分压比和乳酸的测量的影响
7. Combined redox couples for catalytic oxidation of methane by dioxygen at low temperatures [O] . Zengjian An, Xiulian Pan, Xiumei Liu, 2015

机译：组合的氧化还原对在低温下通过分子氧催化氧化甲烷
8. Equilibrium Oxygen Pressures over the Nonstoichiometric Uranium Oxides UO2+X and U3O8-Z at Higher Temperatures [R] . Hagemark, K., Broli, M. 1966

机译：高温下非化学计量的氧化铀UO2 + X和U3O8-Z的平衡氧压力

Catalytic oxidation of alkylbenzenes with molecular oxygen under normal pressure and temperature by N-hydroxyphthalimide combined with Co(Oac)

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