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Aromatic Copolyester-based Nano-biocomposites: Elaboration, Structural Characterization and Properties

机译:基于芳族共聚酯的纳米生物复合材料:精制,结构表征和性能

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摘要

Biodegradable polymers are one of the most promising ways to replace non-degradable polymers. But, to be a real alternative to classical synthetic polymers and find applications, biopolymer (biodegradable polymer) properties have to be enhanced. Nano-biocomposites, which are obtained by incorporation of nanofillers into a biomatrix, are an interesting way to achieve these improvements. Modified and unmodified montmorillonites have been introduced into a biodegradable aromatic copolyester, poly(butyl-ene adipate-co-terephthalate) (PBAT). Structural characterization, thermal and mechanical tests have been carried out to understand better the relations between the nanofillers structuring and the final nano-biocomposite properties. Main results show that clay incorporation and the obtained intercalated structures improve PBAT properties (enhanced thermal stability, increased stiffness) and thus may increase the attractiveness of this biopolymer.
机译:可生物降解的聚合物是取代不可降解聚合物的最有前途的方法之一。但是,要真正替代经典合成聚合物并找到应用,必须增强生物聚合物(可生物降解的聚合物)的性能。通过将纳米填料掺入生物基质中获得的纳米生物复合材料是实现这些改进的有趣方式。已将改性和未改性的蒙脱石引入可生物降解的芳族共聚酯聚己二酸丁二醇酯-对苯二甲酸对苯二甲酸酯(PBAT)中。为了更好地理解纳米填料的结构和最终的纳米生物复合材料之间的关系,已经进行了结构表征,热和机械测试。主要结果表明,粘土的掺入和所获得的插层结构可改善PBAT性能(增强的热稳定性,增强的刚度),因此可提高这种生物聚合物的吸引力。

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