首页> 外文期刊>Journal of Polymers and the Environment >Synthesis, Characterization, and Swelling Behaviors of Poly(acrylic acid-co-acrylamide)/Pozzolan Superabsorbent Polymers
【24h】

Synthesis, Characterization, and Swelling Behaviors of Poly(acrylic acid-co-acrylamide)/Pozzolan Superabsorbent Polymers

机译:聚(丙烯酸-共-丙烯酰胺)/ Pozzolan高吸收性聚合物的合成,表征和溶胀行为

获取原文
获取原文并翻译 | 示例
           

摘要

This article introduces the design and optimization of a new eco-superabsorbent polymer (SAP) aiming to achieve maximum water absorption. In this study, the incorporation of the natural pozzolan (Poz) as an inorganic filler into a SAP was investigated for the first time. A new type of cross-linker, Bis[2-(methacryloyloxy)ethyl] phosphate, was used in the preparation of SAPs. The Taguchi optimization results revealed that factors' level of significance on the water absorption are acrylamide (AAm)acrylic acid (AA)Poz. The optimum levels of factors that provide maximum water absorption are 30.8% AA, 30.8% AAm, and 38.4% of Poz in total weight. This high percentage of Poz in the optimized SAP is the highest ratio of an inorganic filler to a SAP ever mentioned in the literature. The water absorption capacities of the optimized polymer in ultrapure water and saline water were measured as 11,000wt% and 2120wt%, respectively. The overall assessment of FT-IR, XRD, TGA, SEM, and BET studies revealed the successful and homogeneous intercalation of Poz into poly(AA-co-AAm). This new eco-product with enhanced the water absorption capacity and thermal stability can be potentially used as soil conditioners in agricultural activities especially in arid regions.
机译:本文介绍了旨在实现最大吸水率的新型生态超吸收性聚合物(SAP)的设计和优化。在这项研究中,首次研究了将天然火山灰(Poz)作为无机填料掺入SAP中的方法。一种新型的交联剂,双[2-(甲基丙烯酰氧基)乙基]磷酸盐,用于制备SAP。 Taguchi优化结果表明,影响吸水率的重要因素是丙烯酰胺(AAm)>丙烯酸(AA)> Poz。提供最大吸水率的因素的最佳水平为总重量的30.8%AA,30.8%Aam和38.4%的Poz。在优化的SAP中,高含量的Poz是无机填料与SAP比例最高的文献。经优化的聚合物在超纯水和盐水中的吸水能力分别为11,000wt%和2120wt%。 FT-IR,XRD,TGA,SEM和BET研究的总体评估表明,Poz成功并均匀地插入了聚(AA-co-AAm)中。这种具有增强的吸水能力和热稳定性的新型生态产品可以潜在地用作农业活动中的土壤改良剂,特别是在干旱地区。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号