首页> 外文期刊>Journal of Polymers and the Environment >Revealing the Water Resistance, Thermal and Biodegradation Properties of Citrus aurantifolia Crosslinked Tapioca Starch/Nanocellulose Bionanocomposites
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Revealing the Water Resistance, Thermal and Biodegradation Properties of Citrus aurantifolia Crosslinked Tapioca Starch/Nanocellulose Bionanocomposites

机译:揭示柑橘Aurantifolia交联烟草淀粉/纳米纤维糖胺复合材料的耐水性,热和生物降解性能

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摘要

Moisture absorption, thermal and biodegradation properties of nanocellulose (NC) reinforced bionanocomposite tapioca starch (TS) films crosslinked withCitrus aurantifoliaor lime juice (LJ) were investigated for food packaging applications. The films were synthesized by solvent casting using different amounts of nanocellulose and crosslinkers: lime juice and a commercial citric acid (CA). Nanocellulose as reinforcing filler was obtained from oil palm empty fruit bunches through acid hydrolysis. Crystallinity of all TS bionanocomposites was determined using X-ray diffractometry. TS bionanocomposites interaction with water was studied by means of moisture absorption, moisture content and swelling. Flory-Huggin model was used to measure the crosslinked density of crosslinked TS bionanocomposites which indicated successful crosslinking using LJ and CA for TS. The crystallinity of TS film increased from 43.5% for neat TS to 51.6% for TS film with inclusion of NC. LJ-crosslinked TS film with 1 wt% of NC (based on starch content) had the lowest moisture absorption and swelling ratio. TS bionanocomposites with LJ had better thermal and biodegradation properties compared to commercial CA-crosslinked TS biocomposites, which can be a potential food packaging material among the tested bionanocomposites.
机译:研究了纳米纤维素(NC)增强脱硫脱硫脱皮淀粉(TS)膜交联的吸湿性,热和生物降解性能,用于食品包装应用,COLDINALS AURANTIFOLIAORIMICE汁(LJ)。通过使用不同量的纳米纤维素和交联剂的溶剂铸件合成薄膜:石灰汁和商业柠檬酸(CA)。作为增强填料的纳米纤维素是通过酸水解的油棕榈空果实串获得的。使用X射线衍射法测定所有TS脱硫复合物的结晶度。通过吸湿,水分含量和溶胀,研究了与水的脱硫相互作用。使用绒毛密封模型来测量交联的TS脱硫复合材料的交联密度,其指示使用LJ和Ca的成功交联。 TS薄膜的结晶度从纯Ts的43.5%增加至51.6%,对于包含NC的TS膜。具有1wt%的Nc(基于淀粉含量)的LJ交联TS膜具有最低的吸湿和溶胀比。与LJ的TS BionAnoC复合物与商业CA交联的TS生物复合材料相比具有更好的热和生物降解性质,其可以是测试的脱硫复合材料中的潜在食品包装材料。

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