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Utilization of Palm Olein-Based Polyol for Polyurethane Foam Sponge Synthesis: Potential as a Sorbent Material

机译:用于聚氨酯泡沫海绵合成的棕榈油蛋白的多元醇的利用:作为吸附剂材料的潜力

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Polyol was successfully synthesized from natural palm olein and was used as a starting material for polyurethane foam synthesis. FT-IR spectroscopy was used to confirm of each reaction in the multistep synthesis, including the transesterification, epoxidation, and reaction with ethylene glycol, ultimately producing palm olein-based polyol (POBP) and POBP-containing polyurethane foam. The morphological properties of the prepared foams were investigated by scanning electron microscopy. The foam cells were uniform in size and shape, and a coarse cell structure was observed. While the pristine polyurethane foam contained closed cells, the pore structure became more interconnected with the introduction of POBP. The thermal properties were studied by DSC and TGA. In the presence of POBP, the sample was found to be less thermally stable. Mechanical testing revealed that the tensile strength and Young's modulus were decreased, while the elongation at break was increased, suggesting that POBP improved the flexibility of the polyurethane foam. This was in agreement with the observed microstructure. Introducing POBP into the polyurethane foam also decreased the water contact angle from 120 degrees to 80 degrees. However, the oil sorption properties were improved due to interconnected pores along the polyurethane foam structure. Its sorption properties for synthetic dyes (methyl orange and rhodamine B) were also evaluated, and superior sorption properties were found for methyl orange. In short, the polyurethane synthesized from POBP exhibited attractive properties as a sorbent material. The labels in figures (1,3,4,5,6,7,8,9) are not readable. Please provide a new figure with legible labels in Vector EPS or tiff / jpeg format with 600 dpi resolution.Yes, it was provided as a separated file. Graphic
机译:从天然棕榈油蛋白成功地合成多元醇,用作聚氨酯泡沫合成的原料。 FT-IR光谱法用于确认多体合成中的每种反应,包括酯交​​换,环氧化和与乙二醇的反应,最终产生棕榈油基多醇(POBP)和含POBP的聚氨酯泡沫。通过扫描电子显微镜研究制备泡沫的形态学性质。泡沫细胞的尺寸和形状均匀,观察到粗细胞结构。虽然原始聚氨酯泡沫含有闭合细胞,但孔隙结构与引入POBP时变得更加互连。通过DSC和TGA研究了热性质。在POBP存在下,发现样品不太热稳定。机械测试显示拉伸强度和杨氏模量减少,而断裂的伸长率增加,表明pobp改善了聚氨酯泡沫的柔韧性。这与观察到的微观结构一致。将POBP引入聚氨酯泡沫也将水接触角从120度降低至80度。然而,由于沿着聚氨酯泡沫结构互连的孔而改善了油吸附性质。还评估其用于合成染料(甲基橙和罗丹明B)的吸附性能,并发现甲基橙的优异吸附性。简而言之,从pobp合成的聚氨酯表现出具有吸附剂材料的吸引性。图中的标签(1,3,4,5,6,7,9,9)不可读取。请在传染媒介EPS或TIFF / JPEG格式中提供一个新的数字,其中包含600 dpi stoction.yes,它被作为分隔文件提供。形象的

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