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Influence of Different Diss Fiber Treatments over the Properties of Poly Propylene/Recycled and Regenerated Low Density Polyethylene Based Biocomposites

机译:不同散纤纤维处理对聚丙烯/再生和再生低密度聚乙烯基生物复合材料的性能影响

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This study aims the valorization of diss fibers for the production of biocomposites based on blends of recycled and regenerated low density polyethylene (rLDPE) and polypropylene (PP). Thus, the study of different diss fibers treatments was carried out to achieve the best performance of the final biocomposites. The polymeric blends were prepared by using PP/rLDPE (75/25) matrix and adding nano Si particles as reinforcement and maleic anhydride functionalized ethylene copolymer rubber/SiO2(MAC/SiO2) as compatibilizer. Based on this formulation, different biocomposites were prepared by introducing untreated (UDF), thermally treated (TTDF) and chemically treated (CTDF) diss fibers. Several techniques were used for the characterization of the diss fibers and the final biocomposites. The effect of the fiber treatments was assessed by Fourier-transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA). On the other side, the biocomposites were tested for different parameters such as mechanical properties (tensile test) and thermal stability (thermogravimetric analysis and differential scanning calorimetry). Besides other techniques such as X-ray diffraction (XRD) and scanning electron microscopy (SEM) were utilized to determine the morphology of the materials. The final results showed an improvement of the mechanical properties and a satisfactory interfacial adhesion after the introduction of the treated diss fiber into the polymeric matrix, especially in the case of the thermally treated ones. Furthermore, thermal stability was not compromised after the addition of the fibers.
机译:本研究旨在基于再循环和再生低密度聚乙烯(RLDPE)和聚丙烯(PP)的共混物生产用于生产生物复合材料的vAlorization。因此,进行了不同糖纤维处理的研究以实现最终生物复合材料的最佳性能。通过使用PP / RLDPE(75/25)基质并加入纳米Si颗粒作为增强和马来酸酐官能化乙烯共聚物橡胶/ SiO2(MAC / SiO 2)来制备聚合物共混物作为增容剂。基于该配方,通过引入未处理(UDF),热处理(TTDF)和化学处理(CTDF)含水纤维来制备不同的生物复合材料。几种技术用于表征帕纤维和最终生物复合材料。通过傅立叶变换红外光谱(FTIR)和热重分析(TGA)评估纤维处理的效果。在另一边,对不同参数进行测试,例如机械性能(拉伸试验)和热稳定性(热重分析和差示扫描量热法)。除了其他技术,例如X射线衍射(XRD)和扫描电子显微镜(SEM)以确定材料的形态。最终结果表明,在将处理过的散纤纤维引入聚合物基质中后,在聚合物基质中的情况下,尤其是在热处理的纤维中的情况下改善了机械性能和令人满意的界面粘附。此外,添加纤维后,不会损害热稳定性。

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