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首页> 外文期刊>Journal of Polymers and the Environment >Investigation of the Presence and Possible Migration from Microplastics of Phthalic Acid Esters and Polycyclic Aromatic Hydrocarbons
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Investigation of the Presence and Possible Migration from Microplastics of Phthalic Acid Esters and Polycyclic Aromatic Hydrocarbons

机译：从邻苯二甲酸酯和多环芳烃中的微塑料塑料的存在和可能迁移的研究

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摘要

The work detailed here examined the presence and possibility of leaching of phthalic acid esters (PAEs) and polycyclic aromatic hydrocarbons (PAHs) from various products in everyday use. Due to the complicated matrix, which is plastic, extraction parameters should be selected separately each time. The properties of both the extractant and the material selected for testing should also be taken into account, which is very difficult in practice. In addition, when designing new methods, it is particularly important to take into account the principles of green chemistry so as not to burden the environment additionally. For this purpose, it is important to know the factors that affect the extraction of impurities. Therefore, the main objective was to assess the impact of selected environmental conditions on the process by which such pollutants in plastics like polyvinyl chloride (PVC), polystyrene (PS), polypropylene (PP) and rubber migrate. Analysisinter aliaaddressed the impacts of type of plastic, migration time, temperature and microplastic particle size. It proved possible to note the presence in PVC and rubber of both PAEs and PAHs-as substances posing a particular threat to the environment. One of the former is the commonly-used plasticiser di(2-ethylhexyl) phthalate (DEHP), a listed priority hazardous substance under the provisions of Directive 2013/39/EU as regards priority substances in the field of water policy. As monitoring of this substance in the environment indicates amounts that are increasing steadily, the design of effective removal methods needs to start with initial estimates of amounts appearing in the environment over time. Main sources need to be explored, albeit in the certain knowledge that the ubiquitous microplastics are among these,inter aliaas influenced by elution mechanisms. An attempt was also made to identify and characterise other auxiliary substances added to plastics as they are being produced. Indeed, chromatograms and GC/MS spectra suggest leaching of many other plastic substances. Relationships between eluted pollutants were also sought.
机译：这里详述的工作检测了在日常使用中，从各种产品中浸出邻苯二甲酸酯（PAES）和多环芳烃（PAHS）的存在和可能性。由于复杂的矩阵，即塑料，每次都应单独选择提取参数。还应考虑萃取剂和选择用于测试的材料的性质，这在实践中非常困难。此外，在设计新方法时，要考虑到绿色化学原则，特别重要，以免此外的负担。为此目的，了解影响杂质提取的因素非常重要。因此，主要目的是评估所选环境条件对塑料等污染物等过程的影响，如聚氯乙烯（PVC），聚苯乙烯（PS），聚丙烯（PP）和橡胶迁移。 Analysisinter AliaAddressed塑料，迁移时间，温度和微塑性粒度类型的影响。事实证明，可以注意到PVC和PAES和PAHS的橡胶的存在 - 作为对环境构成特殊威胁的物质。其中一个是普通使用的增塑剂二（2-乙基己基）邻苯二甲酸酯（DEHP），在指令2013/39 /欧盟的规定下，关于水政策领域的优先物质的规定，如下规定的优先级危险物质。由于在环境中监测这种物质表明稳定增加的量，有效的去除方法的设计需要从随着时间的推移开始的初始估计。需要探索主要来源，尽管普遍存在的微薄塑料中的某些知识中，但尤其是通过洗脱机制的影响。还尝试识别和表征在生产时添加到塑料中的其他辅助物质。实际上，色谱图和GC / MS光谱表明许多其他塑料物质的浸出。还寻求洗脱污染物之间的关系。

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  • 来源
    《Journal of Polymers and the Environment》 |2021年第2期|599-611|共13页
  • 作者

    Kida Malgorzata; Koszelnik Piotr;

  • 作者单位

    Rzeszow Univ Technol Dept Chem & Environm Engn Fac Civil & Environm Engn & Architecture Al Powstancow Warszawy 6 PL-35959 Rzeszow Poland;

    Rzeszow Univ Technol Dept Chem & Environm Engn Fac Civil & Environm Engn & Architecture Al Powstancow Warszawy 6 PL-35959 Rzeszow Poland;

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  • 正文语种 eng
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  • 关键词

    Microplastics; Polymers; Migration; PAEs; PAHs;

    机译：微塑料;聚合物;迁移;PAES;PAHS;

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