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Synthesis and Properties Modified Feather Keratin-Based Motor Oil Sorbing Cryogels with High Oil Holding Capacity

机译:高持油量的改性羽毛角蛋白基机油分装冰蜡的合成及性能

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摘要

Oleic acid was used to modify keratin extracted from chicken feathers by free radical initiated graft copolymerization. Thereafter, the modified keratin was used for the synthesis of cryogels. The influence of oleic acid modification, the crosslinker content, and the protein concentration on the properties of the cryogels were investigated by Fourier transform infrared spectroscopy, scanning electron microscopy, SDS-PAGE, and through oil holding capacity tests. To enhance the sorption properties, the cryogels were crosslinked with glutaraldehyde. Varying protein concentration from 1.27 to 5.09 wt% and glutaraldehyde concentration from 0 to 5 wt% produced cryogels with oil holding capacity ranging from 4.56 to 10.76 g/g. The highest results exceeded the sorption capacity of previously published oleic acid modified woodchips (6.3 g/g) as well as polypropylene (6 g/g), which is the standard material used in industry.
机译:油酸用于通过自由基引发的接枝共聚作用改性从鸡毛中提取的角蛋白。此后,将修饰的角蛋白用于冷冻凝胶的合成。通过傅立叶变换红外光谱,扫描电子显微镜,SDS-PAGE和持油能力测试,研究了油酸改性,交联剂含量和蛋白质浓度对冷冻凝胶性能的影响。为了增强吸附性能,将冷冻凝胶与戊二醛交联。蛋白质浓度在1.27至5.09 wt%之间变化,戊二醛浓度在0至5 wt%之间变化,生成的冷冻凝胶的持油量为4.56至10.76 g / g。最高结果超过了以前发布的油酸改性木片(6.3 g / g)和聚丙烯(6 g / g)的吸附能力,聚丙烯是工业上使用的标准材料。

著录项

  • 来源
    《Journal of Polymers and the Environment》 |2018年第1期|59-65|共7页
  • 作者单位

    McGill Univ, Dept Bioresource Engn, 21111 Lakeshore Rd, Ste Anne De Bellevue, PQ H9X 3V9, Canada;

    McGill Univ, Dept Bioresource Engn, 21111 Lakeshore Rd, Ste Anne De Bellevue, PQ H9X 3V9, Canada;

    McGill Univ, Dept Bioresource Engn, 21111 Lakeshore Rd, Ste Anne De Bellevue, PQ H9X 3V9, Canada;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Feather; Keratin; Cryogel; Sorbent;

    机译:羽毛;角蛋白;Cryogel;Sorbent;

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