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Improvement of Synthesis and Dielectric Properties of Polyurethane/Mt-QASs(+) (Novel Synthesis)

机译:聚氨酯/ Mt-QASs(+)的合成和介电性能的改进(新颖合成)

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摘要

Polyurethane-based nanocomposites were prepared and their dielectric properties were characterized. Polyurethane (PU) composites were prepared with different organoclay content (1, 3, 5, and 10 wt% for all cases). The composites included quaternary ammonium salts such as 1-methyl-di-octyl-1 phenyl ammonium iodide (QAS-1), 1-methyl-di-nonyl-1 phenyl ammonium iodide (QAS-2), and 1-methyl-di-dodecyl-1 phenyl ammonium iodide (QAS-3) which were newly synthesized for modification of Na+-montmorillonite. Addition of aluminum silicate enhanced the dielectric properties at a constant concentration. Dielectric constants of nanocomposites compounded with 3 %- and 5 %-organoclay were close in value. The characterization of PU/organoclay composites was carried out using Fourier transform infrared and X-ray diffraction.
机译:制备了基于聚氨酯的纳米复合材料,并对其介电性能进行了表征。制备具有不同有机粘土含量(所有情况下分别为1、3、5和10 wt%)的聚氨酯(PU)复合材料。该复合材料包括季铵盐,例如1-甲基-二辛基-1苯基碘化铵(QAS-1),1-甲基-二壬基-1苯基碘化铵(QAS-2)和1-甲基-二甲基合成用于修饰Na +-蒙脱土的-十二烷基-1苯基碘化铵(QAS-3)。硅酸铝的添加在恒定浓度下增强了介电性能。掺有3%和5%有机粘土的纳米复合材料的介电常数值接近。 PU /有机粘土复合材料的表征使用傅里叶变换红外和X射线衍射进行。

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