首页> 外文期刊>Journal of Polymers and the Environment >Melt Flow Behavior in Capillary Extrusion of Nanosized Calcium Carbonate Filled PLLA/PCL Bio-Composites
【24h】

Melt Flow Behavior in Capillary Extrusion of Nanosized Calcium Carbonate Filled PLLA/PCL Bio-Composites

机译:纳米碳酸钙填充的PLLA / PCL生物复合材料在毛细管挤出中的熔体流动行为

获取原文
获取原文并翻译 | 示例
           

摘要

Nanosized calcium carbonate (nano-CaCO_3) filled poly-L-lactide (PLLA)/polycaprolactone (PCL) biocomposites were prepared by using a twin-screw extruder. The melt flow behavior of the composites, including the entry pressure drop, melt shear flow curves and melt shear viscosity were measured through a capillary rheometer operated at a temperature range of 170-200℃and shear rates varying from 50 to 10~3 s~(-1). The melt shear flow roughly followed the power law, while the effect of temperature on the melt shear viscosity might be estimated by using the Arrhenius equation. Moreover, the relationship between the PCL weight fraction and the melt shear viscosity for the PLLA/PCLano-CaCO_3 composite was described by a quadratic equation.
机译:通过使用双螺杆挤出机制备纳米级碳酸钙(nano-CaCO_3)填充的聚-L-丙交酯(PLLA)/聚己内酯(PCL)生物复合材料。通过毛细管流变仪在170-200℃的温度范围内操作,剪切速率在50至10〜3 s〜之间变化,测量了复合材料的熔体流动特性,包括入口压降,熔体剪切流动曲线和熔体剪切粘度。 (-1)。熔体剪切流动大致遵循幂定律,而温度对熔体剪切粘度的影响可通过使用Arrhenius方程估算。此外,通过二次方程式描述了PLLA / PCL /纳米CaCO_3复合材料的PCL重量分数与熔体剪切粘度之间的关系。

著录项

  • 来源
    《Journal of Polymers and the Environment》 |2013年第3期|857-863|共7页
  • 作者单位

    Research Division of Green Function Materials and Equipment, School of Mechanical and Automotive Engineering, South China University of Technology, Guangzhou 510640, People's Republic of China;

    Research Division of Green Function Materials and Equipment, School of Mechanical and Automotive Engineering, South China University of Technology, Guangzhou 510640, People's Republic of China;

    Department of Industrial and Systems Engineering, The Hong Kong Polytechnic University, Kowloon, Hung Horn, Hong Kong, People's Republic of China;

    Department of Industrial and Systems Engineering, The Hong Kong Polytechnic University, Kowloon, Hung Horn, Hong Kong, People's Republic of China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    PLLA; PCL; Nano-CaCO_3; Bio-composites; Melt extrusion; Flow property;

    机译:PLLA;PCL;纳米CaCO_3;生物复合材料;熔融挤出;流动特性;

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号