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New Non-food-Based Composites of Acorn Nutlet and Polycaprolactone: Preparation and Characterization Evaluation

机译:橡果仁和聚己内酯的新型非食品基复合材料:制备和表征评估

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摘要

Two dissimilar renewable resource-based thermoplastic acorn nutlet (TPAN) materials were prepared via twin-screw extrusion with the aid of glycerol or mon-oethanolamine as plasticizers, and then two TPAN/polyc-aprolactone (PCL) composites with different plasticized systems were prepared. Mechanical test showed that glycerol-based composites had excellent tensile properties, and at a PCL content of 50 wt%, their tensile strength and elongation at break reached 14.4 MPa and 1,361 %, respectively. The micro-morphologic investigation of liquid-nitrogen brittle fracture surface indicated certain interface adhesion between glycerol-based thermoplastic acorn nutlet (GTPAN) and PCL. Dynamic mechanical thermal analysis , differential scanning calorimetry and thermogravimetric analysis demonstrated that the weight ratios of TPAN in composites significantly affected the crystallinity, glass transition temperature (T_g), melting temperature (T_m) and thermal stability of composites. Soil burial degradation analysis displayed that all composites had excellent biodegradability. These results demonstrated that GTPAN/PCL composites had superior mechanical and biodegradable properties, enough to partially replace the conventional thermoplastic plastics.
机译:借助甘油或单乙醇胺作为增塑剂,通过双螺杆挤出制备了两种不同的可再生资源基热塑性橡子坚果(TPAN)材料,然后制备了两种具有不同塑化体系的TPAN /聚丙酸内酯(PCL)复合材料。力学测试表明,甘油基复合材料具有出色的拉伸性能,在PCL含量为50 wt%时,其拉伸强度和断裂伸长率分别达到14.4 MPa和1,361%。液氮脆性断裂表面的微观形态研究表明,甘油基热塑性橡子坚果(GTPAN)和PCL之间存在一定的界面粘附性。动态力学热分析,差示扫描量热法和热重分析表明,复合材料中TPAN的重量比显着影响复合材料的结晶度,玻璃化转变温度(T_g),熔融温度(T_m)和热稳定性。土壤埋藏降解分析表明,所有复合材料均具有出色的生物降解性。这些结果表明,GTPAN / PCL复合材料具有优异的机械和生物降解性能,足以部分替代传统的热塑性塑料。

著录项

  • 来源
    《Journal of Polymers and the Environment》 |2013年第4期|1072-1082|共11页
  • 作者单位

    Institute of Chemical Industry of Forestry Products, CAF, Nanjing 210042, China Key Laboratory of Biomass Energy and Material, Nanjing 210042, Jiangsu Province, China National Engineering Laboratory for Biomass Chemical Utilization, Nanjing 210042, China Key and Laboratory on Forest Chemical Engineering, SFA, Nanjing 210042, China Institute of Forest New Technology, CAF, Beijing 100091, China;

    Institute of Chemical Industry of Forestry Products, CAF, Nanjing 210042, China Key Laboratory of Biomass Energy and Material, Nanjing 210042, Jiangsu Province, China National Engineering Laboratory for Biomass Chemical Utilization, Nanjing 210042, China Key and Laboratory on Forest Chemical Engineering, SFA, Nanjing 210042, China Institute of Forest New Technology, CAF, Beijing 100091, China;

    Institute of Chemical Industry of Forestry Products, CAF, Nanjing 210042, China Key Laboratory of Biomass Energy and Material, Nanjing 210042, Jiangsu Province, China National Engineering Laboratory for Biomass Chemical Utilization, Nanjing 210042, China Key and Laboratory on Forest Chemical Engineering, SFA, Nanjing 210042, China Institute of Forest New Technology, CAF, Beijing 100091, China;

    Institute of Chemical Industry of Forestry Products, CAF, Nanjing 210042, China Key Laboratory of Biomass Energy and Material, Nanjing 210042, Jiangsu Province, China National Engineering Laboratory for Biomass Chemical Utilization, Nanjing 210042, China Key and Laboratory on Forest Chemical Engineering, SFA, Nanjing 210042, China Institute of Forest New Technology, CAF, Beijing 100091, China;

    Institute of Chemical Industry of Forestry Products, CAF, Nanjing 210042, China Key Laboratory of Biomass Energy and Material, Nanjing 210042, Jiangsu Province, China National Engineering Laboratory for Biomass Chemical Utilization, Nanjing 210042, China Key and Laboratory on Forest Chemical Engineering, SFA, Nanjing 210042, China Institute of Forest New Technology, CAF, Beijing 100091, China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Acorn nutlet; Polycaprolactone; Twin-screw extrusion method; Composites; Biodegradable properties;

    机译:橡子坚果;聚己内酯;双螺杆挤出法;复合材料;可生物降解的特性;

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