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Ordered mesoporous zirconia microspheres and nanorod arrays for selective hydrogenation of stearic acid

机译:有序的介孔氧化锆微球和纳米棒阵列,用于单酸的选择性氢化

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摘要

The ordered mesoporous zirconia microspheres and nanorod arrays were achieved by manipulating the evaporation rate of the solvent. The crystalline mesoporous walls are tetragonal zirconia. The selective hydrogenation of stearic acid can be catalyzed by the ordered mesoporous zirconia microspheres and nanorod arrays loaded with nickel. The mesoporous zirconia nanorod arrays show high activity because of their large specific surface area and accessible porous structures, and high selectivity owing to the confinement effect of mesoporous channels.
机译:通过操纵溶剂的蒸发速率来实现有序的介孔氧化锆微球和纳米棒阵列。结晶介孔壁是四方氧化锆。硬脂酸的选择性氢化可以通过装载镍的有序的介孔氧化锆微球和纳米棒阵列催化。由于其大的比表面积和可接近的多孔结构,并且由于介孔通道的限制效果,所以介孔氧化锆纳米座阵列显示出高活动。

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