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Aqueous energy-storage cells based on activated carbon and LiMn2O4 electrodes

机译:基于活性炭和LiMn2O4电极的水储能电池

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摘要

In recent years, there has been an increasing need for rechargeable energy-storage devices of many kinds. There are some applications for which energy density is important, whereas for others rate capability (high-power density) and prolonged durability are essential. Batteries address the need for high energy density, while electrochemical capacitors, so called, supercapacitors, can be relevant for the high power density purpose. In between these two kinds of devices, it is possible to develop hybrid systems which possess intermediate properties between supercapacitors and batteries, and which contain both a capacitive or pseudocapacitive electrode and a battery type electrode. With a good selection of electrodes, it is possible to achieve high-rate capability and durability, and also enhanced specific energy density compare to standard supercapacitors. This paper describes the development and study of Li-ion-based hybrid capacitor based on a carbon-based capacitive negative electrode, LiMn2O4 spinel as positive electrode and aqueous solutions with Li2SO4 salt as the electrolyte (pH = 7.5). Here, we demonstrate full hybrid devices as a proof of concept. (C) 2017 Elsevier B.V. All rights reserved.
机译:近年来,对多种可再充电能量存储装置的需求不断增长。在某些应用中,能量密度很重要,而在另一些应用中,速率能力(高功率密度)和持久的耐用性至关重要。电池满足了对高能量密度的需求,而电化学电容器(所谓的超级电容器)可能与高功率密度目的相关。在这两种设备之间,有可能开发出一种混合系统,该混合系统在超级电容器和电池之间具有中间特性,并且同时包含电容性或伪电容性电极和电池型电极。与标准的超级电容器相比,通过良好的电极选择,可以获得高倍率的性能和耐用性,并且还可以提高比能量密度。本文介绍了基于碳基电容性负极,LiMn2O4尖晶石为正极以及以Li2SO4盐为电解质(pH = 7.5)的水溶液为基础的锂离子混合电容器的开发和研究。在这里,我们演示了完整的混合设备作为概念证明。 (C)2017 Elsevier B.V.保留所有权利。

著录项

  • 来源
    《Journal of power sources》 |2017年第30期|148-156|共9页
  • 作者单位

    Bar Ilan Univ, Dept Chem, IL-5290002 Ramat Gan, Israel;

    Bar Ilan Univ, Dept Chem, IL-5290002 Ramat Gan, Israel;

    Univ Nantes, CNRS, Inst Mat Jean Rouxel IMN, F-44322 Nantes 3, France|FR CNRS, Reseau Stockage Electrochim Energie RS2E, Paris, France;

    Bar Ilan Univ, Dept Chem, IL-5290002 Ramat Gan, Israel;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Li-ion capacitors; Hybrid capacitors; LiMn2O4 (spinel); Aqueous electrolyte;

    机译:锂离子电容器;混合电容器;LiMn2O4(尖晶石);水电解质;

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