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首页> 外文期刊>Journal of power sources >Novel niobium carbide/carbon porous nanotube electrocatalyst supports for proton exchange membrane fuel cell cathodes
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Novel niobium carbide/carbon porous nanotube electrocatalyst supports for proton exchange membrane fuel cell cathodes

机译:用于质子交换膜燃料电池阴极的新型碳化铌/碳多孔纳米管电催化剂载体

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摘要

Niobium carbide/carbon nanotubular porous structures have been prepared using electrospinning and used as electrocatalyst supports for proton exchange membrane fuel cells. They were functionalised with 3.1 nm Pt particles synthesised by a microwave-assisted polyol method and characterised for their electrochemical properties. The novel NbC-based electrocatalyst demonstrated electroactivity towards the oxygen reduction reaction as well as greater stability over high potential cycling than a commercial carbon-based electrocatalyst. Pt/Nbc/c was integrated at the cathode of a membrane electrode assembly and characterised in a single fuel cell showing promising activity and power density. (C) 2017 Elsevier B.V. All rights reserved.
机译:碳化铌/碳纳米管多孔结构已经使用电纺丝制备,并且用作质子交换膜燃料电池的电催化剂载体。将它们用通过微波辅助多元醇法合成的3.1 nm Pt颗粒进行功能化,并对其电化学性质进行表征。新型的基于NbC的电催化剂表现出了对氧还原反应的电活性,并且在高电势循环下具有比商用碳基电催化剂更高的稳定性。 Pt / Nbc / c集成在膜电极组件的阴极,其特征在于单个燃料电池显示出有希望的活性和功率密度。 (C)2017 Elsevier B.V.保留所有权利。

著录项

  • 来源
    《Journal of power sources》 |2017年第30期|20-26|共7页
  • 作者单位

    Univ Montpellier, UMR CNRS Agregats Interfaces Mat Energie 5253, Inst Charles Gerhardt Montpellier, F-34095 Montpellier, France;

    Univ Montpellier, UMR CNRS Agregats Interfaces Mat Energie 5253, Inst Charles Gerhardt Montpellier, F-34095 Montpellier, France;

    Johnson Matthey Technol Ctr, Reading RG4 9NH, Berks, England;

    Johnson Matthey Technol Ctr, Reading RG4 9NH, Berks, England;

    Univ Montpellier, UMR CNRS Agregats Interfaces Mat Energie 5253, Inst Charles Gerhardt Montpellier, F-34095 Montpellier, France;

    Univ Montpellier, UMR CNRS Agregats Interfaces Mat Energie 5253, Inst Charles Gerhardt Montpellier, F-34095 Montpellier, France;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Niobium carbide; Electrocatalyst support; Proton exchange membrane fuel cell; Oxygen reduction reaction; Electrospinning;

    机译:碳化铌;电催化剂载体;质子交换膜燃料电池;氧还原反应;静电纺丝;

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