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首页> 外文期刊>Journal of power sources >SrFe_(0.75)Mo_(0.25)O_(3-δ) impregnated 430L alloys for efficient fuel oxidation in metal supported solid oxide fuel cells
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SrFe_(0.75)Mo_(0.25)O_(3-δ) impregnated 430L alloys for efficient fuel oxidation in metal supported solid oxide fuel cells

机译:SrFe_(0.75)Mo_(0.25)O_(3-δ)浸渍的430L合金,可在金属支撑的固体氧化物燃料电池中有效地进行燃料氧化

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摘要

Here we report a novel SrFe_(0.75)Mo_(0.25)O_(3-δ) (SFMO)-430L composite anode for the application in the metal supported solid oxide fuel cells. Such an anode is prepared by coating a thin nano porous and mixed electronic-ionic conducting SFMO layer onto the internal surface of a micron porous 430L alloy backbone. The area specific polarization resistance of the composite anode for hydrogen oxidation can be as low as 0.11 Ω cm~2 at 800 ℃. The electronic conductivity of the 430L alloy support is found to be critically important for promoting rapid hydrogen oxidation kinetics and attaining such a low polarization resistance as the fuel cell anode. A metal-supported fuel cell with the SFMO impregnated 430L composite anode exhibits outstanding power densities at 800 ℃, e.g., 0.81 W cm~(-2) in hydrogen and 0.31 W cm~(-2) in iso-octane. Preliminary results show that the present SFMO-430L composite anode exhibits much higher tolerance for coking formation than the traditional Ni-based anode.
机译:在这里,我们报告了一种新颖的SrFe_(0.75)Mo_(0.25)O_(3-δ)(SFMO)-430L复合阳极,用于在金属支撑的固体氧化物燃料电池中的应用。通过在纳米多孔430L合金主链的内表面上涂覆纳米多孔和混合的电子离子导电SFMO薄层来制备这种阳极。复合阳极在800℃下的氢氧化比极化电阻可低至0.11Ωcm〜2。发现430L合金载体的电子导电性对于促进快速氢氧化动力学并获得像燃料电池阳极这样的低极化电阻至关重要。 SFMO浸渍430L复合阳极的金属支撑燃料电池在800℃时具有出色的功率密度,例如在氢气中为0.81 W cm〜(-2),在异辛烷中为0.31 W cm〜(-2)。初步结果表明,与传统的镍基阳极相比,本发明的SFMO-430L复合阳极对结焦的耐受性更高。

著录项

  • 来源
    《Journal of power sources》 |2014年第10期|244-249|共6页
  • 作者单位

    CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS), 1295 Dingxi Road, Shanghai 200050, PR China;

    CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS), 1295 Dingxi Road, Shanghai 200050, PR China;

    CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS), 1295 Dingxi Road, Shanghai 200050, PR China;

    CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS), 1295 Dingxi Road, Shanghai 200050, PR China;

    CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS), 1295 Dingxi Road, Shanghai 200050, PR China;

    CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS), 1295 Dingxi Road, Shanghai 200050, PR China;

    CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS), 1295 Dingxi Road, Shanghai 200050, PR China;

    CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS), 1295 Dingxi Road, Shanghai 200050, PR China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Metal-supported solid oxide fuel cell; Impregnation; Anode; Molybdenum doped strontium ferrite;

    机译:金属支撑的固体氧化物燃料电池;浸渍阳极;钼掺杂锶铁氧体;

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