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Ni-Mn based alloys as versatile catalyst for different electrochemical reactions

机译:Ni-Mn基合金可作为多种电化学反应的多功能催化剂

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摘要

To develop large scale use of hydrogen and fuel cells as a renewable energy source it is need to increase their durability and reduce their cost mainly due to the use of precious metals. We have examined new type of the low cost binary nickel-manganese (Ni-Mn) catalysts electrodeposited from ammonium chloride bath onto copper substrates. By varying bath composition, polarization potential and essentially bath temperature the operating deposition conditions were optimized to produce Ni-Mn coatings with high active surface (e.g. spongy aspect). The outstanding catalytic activity, the durability and the versatility of the deposited films have been characterized in basic media using several electrochemical processes, such as hydrogen evolution reaction (HER), water oxidation reaction (OER) and ethanol oxidation reaction (EOR).
机译:为了大量使用氢和燃料电池作为可再生能源,主要由于使用贵金属,需要提高其耐久性并降低其成本。我们已经研究了新型的低成本二元镍锰(Ni-Mn)催化剂,该催化剂是从氯化铵浴中电解沉积到铜基板上的。通过改变镀液组成,极化电势和基本镀液温度,优化了操作沉积条件以生产具有高活性表面(例如海绵状)的Ni-Mn涂层。在碱性介质中,已使用几种电化学方法(例如析氢反应(HER),水氧化反应(OER)和乙醇氧化反应(EOR))在碱性介质中表征了沉积膜的出色催化活性,耐久性和多功能性。

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