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High-strength all-solid lithium ion electrodes based on Li_4Ti_5Oi_2

机译:基于Li_4Ti_5Oi_2的高强度全固态锂离子电极

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摘要

A Li_4Ti_5O_(12)-Li_(0.29)La_(0.57)TiO_3-Ag electrode composite was fabricated via sintering the corresponding powder mixture. The process achieved a final relative density of 97% the theoretical. Relatively thick, ~100 靘, electrodes were fabricated to enhance the energy density relatively to the traditional solid-state thin film battery electrodes. The sintered electrode composite delivered full capacity in the first discharge at C/40 discharge rate. Full capacity utilization resulted from the 3D percolated network of both solid electrolyte and metal, which provide paths for ionic and electronic transport, respectively. The electrodes retained 85% of the theoretical capacity after 10 cycles at C/40 discharge rate. The tensile strength and the Young's modulus of the sintered electrode composite are the highest reported values to date, and are at least an order of magnitude higher than the corresponding value of traditional tapecast "composite electrodes". The results demonstrate the concept of utilizing thick all-solid electrodes for high-strength batteries, which might be used as multifunctional structural and energy storage materials.
机译:通过烧结相应的粉末混合物,制备了Li_4Ti_5O_(12)-Li_(0.29)La_(0.57)TiO_3-Ag电极复合材料。该方法的最终相对密度为理论值的97%。与传统的固态薄膜电池电极相比,制造了相对较厚的〜100 electrodes电极来提高能量密度。烧结的电极复合材料在第一次放电中以C / 40放电速率输送了全部容量。固体电解质和金属的3D渗滤网络可充分利用容量,它们分别为离子和电子传输提供了路径。在C / 40放电速率下10个循环后,电极保留了理论容量的85%。烧结电极复合材料的拉伸强度和杨氏模量是迄今报道的最高值,并且比传统的流延“复合电极”的相应值高至少一个数量级。结果证明了将厚的全固态电极用于高强度电池的概念,该电极可用作多功能结构和储能材料。

著录项

  • 来源
    《Journal of power sources》 |2011年第15期|p.6507-6511|共5页
  • 作者单位

    Department of Materials Science and Engineering. Massachusetts Institute of Technology, Cambridge, MA 02139. United States,Department of Materials Science and Engineering. Massachusetts Institute of Technology, Cambridge, MA 02139. United States;

    Department of Aerospace Engineering, University of Illinois at Urbana-Champaign, Urbana, IL 61801, United States;

    Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign. Urbana, IL 61801, United States;

    Department of Aerospace Engineering, University of Illinois at Urbana-Champaign, Urbana, IL 61801, United States;

    Department of Materials Science and Engineering. Massachusetts Institute of Technology, Cambridge, MA 02139. United States;

    Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign. Urbana, IL 61801, United States;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    li-ion battery; electrode; li_4ti_5o_(12); solid electrolyte; strength; sintering;

    机译:锂离子电池电极;li_4ti_5o_(12);固体电解质强度;烧结;

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