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On the single chamber solid oxide fuel cells

机译:在单室固体氧化物燃料电池上

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摘要

Single chamber solid oxide fuel cells, SC-SOFCs, design and performance is discussed. It is shown that all of them operate on non-selective anodes. They operate on cathodes that become selective only under short residence times. As a result these cells are not functioning as true mixed reactant solid oxide fuel cells (MR-SOFC). The lack of selectivity is a serious draw back. True MR-SOFC can be constructed in ways that make them cheaper in fabrication, providing high power density, high fuel utilization and reduced explosion risk. The fact that SOFCs operate in a single cell is a necessary but not sufficient condition for the proper operation of MR-SOFCs. The selectivity looked for the anode and cathode is of a special kind. It selects between electrochemical and chemical reactions, preferring the first ones. Results reported here suggest that MR-SOFC can operate only up to ~600℃. At these relative low temperatures, materials other than oxides can also be considered for use. Future directions in the needed research in order to develop true MR-SOFCs are discussed.
机译:讨论了单室固体氧化物燃料电池,SC-SOFC,设计和性能。结果表明,它们全部在非选择性阳极上运行。它们在仅在短停留时间下具有选择性的阴极上运行。结果,这些电池不能用作真正的混合反应物固体氧化物燃料电池(MR-SOFC)。缺乏选择性是一个严重的缺点。真正的MR-SOFC可以通过使其制造成本更低,提供高功率密度,高燃料利用率和降低爆炸风险的方式构造。 SOMR在单个单元中运行这一事实是MR-SOFC正常运行的必要条件,但不是充分条件。寻找阳极和阴极的选择性是一种特殊的选择。它在电化学反应和化学反应之间进行选择,优先选择第一个反应。此处报道的结果表明,MR-SOFC只能在〜600℃的温度下工作。在这些相对较低的温度下,也可以考虑使用氧化物以外的材料。讨论了开发真正的MR-SOFC所需研究的未来方向。

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