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首页> 外文期刊>Journal of power sources >Hydrogen production through steam electrolysis: Control strategies for a cathode-supported intermediate temperature solid oxide electrolysis cell
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Hydrogen production through steam electrolysis: Control strategies for a cathode-supported intermediate temperature solid oxide electrolysis cell

机译:通过蒸汽电解制氢:阴极支撑的中温固体氧化物电解槽的控制策略

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摘要

Hydrogen production via steam electrolysis may involve less electrical energy consumption than conventional low temperature water electrolysis, reflecting the favourable thermodynamics and kinetics at elevated temperatures. The present paper reports on the development of a one-dimensional dynamic model of a cathode-supported planar intermediate temperature solid oxide electrolysis cell (SOEC) stack with air flow introduced through the cells. The model, which consists of an electrochemical model, two mass balances, and four energy balances, is here employed to study the prospect of the stack temperature control through the variation of the air flow rate. The simulations found that the increase in the air flow rate provides enhanced cooling and heating during exothermic and endothermic operations, respectively. The stack behaviour has suggested that such a convective heat transfer between the cell components and air flow would allow the control of stack temperature. However, only a small dependence of the temperature on the air flow rate was observed for a stack driven at conditions near thermoneutral operation, indicating that this operating mode should be avoided from a control perspective.
机译:与常规的低温水电解法相比,通过蒸汽电解法制氢所涉及的电能消耗更少,这反映了高温下有利的热力学和动力学。本文报道了阴极支撑的平面中温固体氧化物电解槽(SOEC)电池堆的一维动力学模型的发展,其中通过电池引入了气流。该模型由电化学模型,两个质量平衡和四个能量平衡组成,此处用于研究通过改变空气流速来控制烟囱温度的前景。模拟发现,空气流量的增加分别在放热和吸热操作期间提供了增强的冷却和加热。电池组的性能表明,电池组件之间的这种对流传热和空气流动将允许控制电池组温度。然而,对于在接近热中性操作的条件下驱动的烟囱,仅观察到温度对空气流速的很小依赖性,这表明从控制角度来看应避免这种操作模式。

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