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首页> 外文期刊>Journal of power sources >Characterisation Of Porous Carbon Electrode Materials Used In Proton Exchange Membrane Fuel Cells Via Gas Adsorption
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Characterisation Of Porous Carbon Electrode Materials Used In Proton Exchange Membrane Fuel Cells Via Gas Adsorption

机译:质子交换膜燃料电池中多孔碳电极材料的气体吸附特性

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摘要

Porous carbon materials are typically used in both the substrate (typically carbon paper) and the elec-trocatalyst supports (often platinised carbon) within proton exchange membrane fuel cells. Gravimetric nitrogen adsorption has been studied at a carbon paper substrate, two different Pt-loaded carbon paper electrodes and three particulate carbon blacks. N_2 BET surface areas and surface fractal dimensions were determined using the fractal BET and Frenkel-Halsey-Hill models for all but one of the materials studied. The fractal dimensions of the carbon blacks obtained from gas adsorption were compared with those obtained independently by small angle X-ray scattering and showed good agreement. Density functional theory was used to characterise one of the carbon blacks, as the standard BET model was not applicable.
机译:质子交换膜燃料电池中的基材(通常为碳纸)和电催化剂载体(通常为铂碳)通常都使用多孔碳材料。已经研究了在碳纸基材,两种不同的Pt负载碳纸电极和三种颗粒炭黑中的重量氮吸附。使用分形BET和Frenkel-Halsey-Hill模型(除一种研究材料外)确定N_2 BET表面积和表面分形维数。将通过气体吸附获得的炭黑的分形维数与通过小角度X射线散射独立获得的分形维数进行了比较,并显示出良好的一致性。由于标准BET模型不适用,因此使用密度泛函理论来表征一种炭黑。

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