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Improvement of the performances of tubular solid oxide fuel cells by optimizing co-sintering temperature of the NiO/YSZ anode-YSZ electrolyte double layers

机译:通过优化NiO / YSZ阳极-YSZ电解质双层的共烧结温度来改善管状固体氧化物燃料电池的性能

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摘要

The effects of co-sintering temperature on anode microstructure, electrolyte film microstructure, and final cell performance of tubular solid oxide fuel cells (SOFCs) were fully studied. The co-sintering of the NiO/YSZ anode-YSZ electrolyte double layers at temperature ranging from 1350 to 1400 ℃ for 5 h was carried out. Porosity and electrical conductivity were measured to examine the anodes microstructure, and the electrolyte films microstructure were characterized by scanning electronic microscope (SEM). A higher open current voltage (OCV) value of 0.99 V was achieved by co-sintering the cell at 1400 ℃ indicating denser electrolyte film, while the maximum power density of the cell co-sintered at 1380 ℃ was achieved with 322 mW cm~(-2) at 800 ℃, which was higher than that (241.3 mW cm~(-2)) of the cell co-sintered at 1400 ℃ because of better anode microstructure.
机译:充分研究了共烧结温度对管状固体氧化物燃料电池(SOFC)的阳极微结构,电解质膜微结构和最终电池性能的影响。 NiO / YSZ阳极-YSZ电解质双层在1350-1400℃的温度下共烧结5h。测量孔隙率和电导率以检查阳极的微观结构,并且通过扫描电子显微镜(SEM)表征电解质膜的微观结构。通过在1400℃共烧结电池,可得到0.99 V的较高开路电压(OCV)值,表明电解质膜更致密,而在1380℃共烧结电池的最大功率密度为322 mW cm〜( -2)在800℃时,由于阳极微观结构更好,高于在1400℃共烧结的电池(241.3 mW cm〜(-2))。

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