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首页> 外文期刊>Journal of power sources >Ionic conductivity measurements of molten iodide-based electrolytes
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Ionic conductivity measurements of molten iodide-based electrolytes

机译:熔融碘化物电解质的离子电导率测量

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A number of iodide-based electrolytes (LiCl-LiI, Lil-KI, LiCl-LiBr-LiI, LiCl-Lil-KI and LiF-LiCl-LiI) were considered to be used in thermal batteries. Ionic conductivity of multi-cation and all-lithium electrolytes were evaluated. They were compared to the classical electrolytes (LiCl-KCl, LiF-LiBr-KBr and LiF-LiCl-LiBr) used in thermal battery applications. Measurements were realised by electrochemical impedance spectroscopy (E.I.S.). It was shown that some all-lithium iodide-based electrolytes exhibit interesting ionic conductivities and are suitable as electrolytes in thermal batteries. It was pointed out that activation energy E_a was close to 11 kJmol~(-1) for multi-cation electrolytes, whereas it was equal to 7kJmol~(-1) for all-lithium electrolytes.
机译:大量的基于碘化物的电解质(LiCl-LiI,Lil-KI,LiCl-LiBr-LiI,LiCl-Lil-KI和LiF-LiCl-LiI)被认为用于热电池。评估了多阳离子和全锂电解质的离子电导率。将它们与热电池应用中使用的传统电解质(LiCl-KCl,LiF-LiBr-KBr和LiF-LiCl-LiBr)进行了比较。通过电化学阻抗光谱法(E.I.S.)实现测量。结果表明,某些全碘化锂基电解质表现出令人关注的离子电导率,适合用作热电池中的电解质。指出多阳离子电解质的活化能E_a接近11 kJmol〜(-1),而全锂电解质的活化能E_a等于7kJmol〜(-1)。

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